2,2'-BIPYRIDINE-3,3'-DICARBONITRILE

Base Information

• Chemical Name: 2,2'-BIPYRIDINE-3,3'-DICARBONITRILE
• CAS No.: 136869-49-3
• Molecular Formula: C12H6N4
• Molecular Weight: 206.2
• Hs Code.: 2933399090
• Mol file: 136869-49-3.mol

Synonyms:2-(3-cyanopyridin-2-yl)pyridine-3-carbonitrile;

Chemical Property of 2,2'-BIPYRIDINE-3,3'-DICARBONITRILE

Chemical Property:

• Boiling Point: 447.0±45.0 °C(Predicted)
• PKA: 0.07±0.32(Predicted)
• PSA: 73.36000
• Density: 1.32±0.1 g/cm3(Predicted)
• LogP: 1.88696

Purity/Quality:

98%Min ^*data from raw suppliers

2,2''-Bipyridine-3,3''-dicarbonitrile ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,2'-BIPYRIDINE-3,3'-DICARBONITRILE

There total 1 articles about 2,2'-BIPYRIDINE-3,3'-DICARBONITRILE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

2-bromonicotinonitrile (20577-26-8) → 3,3′-dicyano-2,2′-bipyridine (136869-49-3)

Guidance literature:

With copper; In N,N-dimethyl-formamide; at 150 ℃;

DOI:10.1039/c39910001135

Reference yield: 2.1%

4,5-bis(4-tert-butylphenoxy)-1,2-dicyanobenzene + 3,3′-dicyano-2,2′-bipyridine (136869-49-3) → Ni[C32H8N8(OC6H4C4H9)8] + C96H90N10NiO6 (1354049-23-2)

Guidance literature:

With quinoline; ammonium molibdate; nickel diacetate; at 330 ℃; for 0.333333h;

DOI:10.1016/j.tetlet.2011.11.092

Reference yield:

3,3′-dicyano-2,2′-bipyridine (136869-49-3) → 3,3'-bis(hydroxycarbonyl)-2,2'-bipyridine (4433-01-6)

Guidance literature:

With potassium hydroxide; In acetonitrile;

DOI:10.1016/0022-328X(94)05058-J

upstream raw materials:

2-bromonicotinonitrile

Downstream raw materials:

3,3'-bis(hydroxycarbonyl)-2,2'-bipyridine

C₉₆H₉₀N₁₀NiO₆

Refernces