(11bS)-N,N-Bis[(S)-(+)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

Base Information

Chemical Name:(11bS)-N,N-Bis[(S)-(+)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
CAS No.:776316-48-4
Molecular Formula:C₃₈H₃₄NO₄P
Molecular Weight:599.666
Hs Code.:
European Community (EC) Number:811-452-0
Nikkaji Number:J2.090.738J,J2.924.142B,J2.164.164B
Mol file:776316-48-4.mol

Synonyms:776316-48-4;(11bS)-N,N-Bis[(S)-(+)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;(11bR)-N,N-Bis[(1S)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;776316-53-1;N,N-Bis((S)-1-(2-methoxyphenyl)ethyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;SCHEMBL17513108;MFCD17018757;CS-0088090;N,N-Bis[(1S)-1-(2-methoxyphenyl)ethyl]-12,14-dioxa-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-amine

Suppliers and Price of (11bS)-N,N-Bis[(S)-(+)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
(11bS)-N,N-Bis[(S)-(+)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, min. 98%
500mg
$ 524.00

Strem Chemicals
(11bS)-N,N-Bis[(S)-(+)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, min. 98%
100mg
$ 145.00

Total 4 raw suppliers

Chemical Property of (11bS)-N,N-Bis[(S)-(+)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

Chemical Property:

Boiling Point:760.0±70.0 °C(Predicted)
PKA:-0.37±0.20(Predicted)
Sensitive.:moisture sensitive
XLogP3:9.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:7
Exact Mass:599.22254556
Heavy Atom Count:44
Complexity:851

Purity/Quality:

97% ^*data from raw suppliers

(11bS)-N,N-Bis[(S)-(+)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, min. 98% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(C1=CC=CC=C1OC)N(C(C)C2=CC=CC=C2OC)P3OC4=C(C5=CC=CC=C5C=C4)C6=C(O3)C=CC7=CC=CC=C76
Isomeric SMILES:C[C@@H](C1=CC=CC=C1OC)N([C@@H](C)C2=CC=CC=C2OC)P3OC4=C(C5=CC=CC=C5C=C4)C6=C(O3)C=CC7=CC=CC=C76

Technology Process of (11bS)-N,N-Bis[(S)-(+)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

There total 13 articles about (11bS)-N,N-Bis[(S)-(+)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 18531-99-2
(S)-[1,1']-binaphthalenyl-2,2'-diol

: 280107-26-8
bis-[(R)-1-(2-methoxyphenyl)ethyl]amine

: 776316-48-4
O,O’-(R)-1,1’-(dinaphthyl-2,2’-diyl)-N,N’-di-(R,R)-1-(2-methoxyphenyl)ethylphosphoramidite

Guidance literature:: bis-[(R)-1-(2-methoxyphenyl)ethyl]amine; With triethylamine; phosphorus trichloride; In tetrahydrofuran; at -78 - 20 ℃; for 4h; Inert atmosphere;

(S)-[1,1']-binaphthalenyl-2,2'-diol; In tetrahydrofuran; for 16h; Inert atmosphere;
DOI:10.1021/jacs.0c01700