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Technology Process of Quinolinium

Quinolinium

Base Information
  • Chemical Name:Quinolinium
  • CAS No.:22559-70-2
  • Molecular Formula:C9H8N
  • Molecular Weight:130.169
  • Hs Code.:2933499090
  • DSSTox Substance ID:DTXSID60879830
  • Nikkaji Number:J1.726.690J,J136.387E
  • Mol file:22559-70-2.mol
Quinolinium

Synonyms:Quinolinium;22559-70-2;DTXSID60879830;SMWDFEZZVXVKRB-UHFFFAOYSA-O

Suppliers and Price of Quinolinium
Supply Marketing:
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • American Custom Chemicals Corporation
  • 1,1'-(1,14-TETRADECANEDIYL) BIS DIIODIDE 95.00%
  • 5MG
  • $ 505.66
Total 3 raw suppliers
Chemical Property of Quinolinium
Chemical Property:
  • PSA：12.89000 
  • LogP:2.23480 
  • Storage Temp.:-20°C 
  • XLogP3:2.5
  • Hydrogen Bond Donor Count:1
  • Hydrogen Bond Acceptor Count:0
  • Rotatable Bond Count:0
  • Exact Mass:130.065674259
  • Heavy Atom Count:10
  • Complexity:111
Purity/Quality:

99% *data from raw suppliers

1,1'-(1,14-TETRADECANEDIYL) BIS DIIODIDE 95.00% *data from reagent suppliers

Safty Information:
  • Pictogram(s):  
  • Hazard Codes:Xi 
  • Statements: 36/37/38 
  • Safety Statements: 26-36 
MSDS Files:
Useful:
  • Canonical SMILES:C1=CC=C2C(=C1)C=CC=[NH+]2
Technology Process of Quinolinium

There total 1 articles about Quinolinium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

quinoline
91-22-5

quinoline

quinolinium
22559-70-2

quinolinium

Guidance literature:
With trifluoroacetic acid; In [D3]acetonitrile; at 24.84 ℃;
DOI:10.1039/c7cc07469g
upstream raw materials:

quinoline

Refernces

Primary kinetic isotope effects on hydride transfer from 1,3-dimethyl-2-phenylbenzimidazoline to NAD+ analogues

10.1021/ja004232+

The research investigates the primary kinetic isotope effects (KIE) for hydride transfer reactions between NAD+ analogues (pyridinium, quinolinium, phenanthridinium, and acridinium ions) and 1,3-dimethyl-2-phenylbenzimidazoline in a 4:1 mixture of 2-propanol and water at 25 °C. The study finds that the KIE values systematically vary from 6.27 to 4.06 as the equilibrium constant changes from around 10 to 10^12. This variation is consistent with Marcus theory, which assumes no high-energy intermediates and suggests that the perpendicular effect, arising from changes in bond distances and orders in critical complexes, is primarily responsible for the observed changes in KIE. The parallel effect (Leffler-Hammond effect) contributes less due to the high intrinsic barrier. The study supports Marcus theory's applicability to hydride transfer reactions and highlights the significant role of corner-cutting tunneling in hydrogen transfer reactions.

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