Phenyldipiperidinophosphine

Base Information

• Chemical Name: Phenyldipiperidinophosphine
• CAS No.: 14287-62-8
• Molecular Formula: C₁₆H₂₅N₂P
• Molecular Weight: 276.362
• Hs Code.: 2933399090
• DSSTox Substance ID: DTXSID10162204
• Nikkaji Number: J50.228F
• Wikidata: Q83030791
• Mol file: 14287-62-8.mol

Synonyms:Phenyldipiperidinophosphine;14287-62-8;Phenylphosphonous dipiperidide;Phosphine, phenyl (di-1-piperidyl)-;BRN 0237646;Phenyl (di-1-piperidyl)phosphine;phenyl-di(piperidin-1-yl)phosphane;Phenylbispiperidinophosphine;Piperidine, 1,1'-(phenylphosphinidene)bis-;Piperidine, 1,1'-(phenylphosphinidene)di-;0-20-00-00084 (Beilstein Handbook Reference);dipiperidino phenylphosphine;SCHEMBL6901641;C16H25N2P;DTXSID10162204;C16-H25-N2-P;LS-106060;Piperidine, 1,1'-(phenylphosphinidene)di- (6CI,7CI,8CI)

Chemical Property of Phenyldipiperidinophosphine

Chemical Property:

• Boiling Point: 399.6°Cat760mmHg
• Flash Point: 195.5°C
• PSA: 20.07000
• Density: g/cm³
• LogP: 3.47140
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 276.175535804
• Heavy Atom Count: 19
• Complexity: 236

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCN(CC1)P(C2=CC=CC=C2)N3CCCCC3

Technology Process of Phenyldipiperidinophosphine

There total 2 articles about Phenyldipiperidinophosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

piperidine (110-89-4) + Dichlorophenylphosphine (644-97-3) → 1-[phenyl(piperidin-1-yl)phosphanyl]piperidine (14287-62-8)

Guidance literature:

With diethyl ether;

Reference yield:

→ 1-[phenyl(piperidin-1-yl)phosphanyl]piperidine (14287-62-8)

Guidance literature:

aus Dichlor-phenyl-phosphin, 1) Piperidin in Bzl. , 2) Abtr. des ausgeschied. Piperidin*Hydrochlorid;

DOI:10.1021/jo01062a050

Reference yield: 85.0%

1-[phenyl(piperidin-1-yl)phosphanyl]piperidine (14287-62-8) + bis(diisopropylamino)cyclopropenium tetrafluoroborate → (Z)-((3-(diisopropylamino)-1-isopropyl-4,4-dimethylazetidin-2-ylidene)methyl)(phenyl)di(piperidin-1-yl)phosphonium tetrafluoroborate

Guidance literature:

In tetrahydrofuran; at 60 ℃; for 24h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.joc.0c00847

upstream raw materials:

piperidine

Dichlorophenylphosphine