Methyl 3-aMino-2,4-diMethylbenzoate

Base Information

• Chemical Name: Methyl 3-aMino-2,4-diMethylbenzoate
• CAS No.: 24812-89-3
• Molecular Formula: C10H13NO2
• Molecular Weight: 179.219
• Hs Code.: 2922499990
• Mol file: 24812-89-3.mol

Synonyms:Methyl 3-aMino-2,4-diMethylbenzoate;Benzoic acid, 3-aMino-2,4-diMethyl-, Methyl ester

Chemical Property of Methyl 3-aMino-2,4-diMethylbenzoate

Chemical Property:

• Boiling Point: 299.7±35.0 °C(Predicted)
• PKA: 3.16±0.10(Predicted)
• PSA: 52.32000
• Density: 1.105±0.06 g/cm3(Predicted)
• LogP: 2.25340
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C

Purity/Quality:

97% ^*data from raw suppliers

Methyl3-amino-2,4-dimethylbenzoate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methyl 3-aMino-2,4-diMethylbenzoate

There total 3 articles about Methyl 3-aMino-2,4-diMethylbenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

methyl 2,4-dimethyl-3-nitro-benzoate (24805-54-7) → methyl 3-amino-2,4-dimethyl-benzoate (24812-89-3)

Guidance literature:

With palladium 10% on activated carbon; hydrogen; In methanol; for 144h;

Reference yield:

2,6-dimethylnitrobenzene (81-20-9) → methyl 3-amino-2,4-dimethyl-benzoate (24812-89-3)

Guidance literature:

Multi-step reaction with 3 steps

1: iodine; periodic acid / sulfuric acid; acetic acid / 168 h / 90 °C

2: palladium diacetate; 1,4-di(diphenylphosphino)-butane; triethylamine / acetonitrile / 2 h / 100 °C / 4137.41 Torr / Autoclave; Sealed tube

3: palladium 10% on activated carbon; hydrogen / methanol / 144 h

With palladium 10% on activated carbon; hydrogen; iodine; palladium diacetate; periodic acid; triethylamine; 1,4-di(diphenylphosphino)-butane; In methanol; sulfuric acid; acetic acid; acetonitrile;

Reference yield:

1-iodo-2,4-dimethyl-3-nitro-benzene (56404-21-8) → methyl 3-amino-2,4-dimethyl-benzoate (24812-89-3)

Guidance literature:

Multi-step reaction with 2 steps

1: palladium diacetate; 1,4-di(diphenylphosphino)-butane; triethylamine / acetonitrile / 2 h / 100 °C / 4137.41 Torr / Autoclave; Sealed tube

2: palladium 10% on activated carbon; hydrogen / methanol / 144 h

With palladium 10% on activated carbon; hydrogen; palladium diacetate; triethylamine; 1,4-di(diphenylphosphino)-butane; In methanol; acetonitrile;

upstream raw materials:

2,6-dimethylnitrobenzene

1-iodo-2,4-dimethyl-3-nitro-benzene

methyl 2,4-dimethyl-3-nitro-benzoate

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