(Z)-12-(Tetrahydro-2H-pyran-2-yloxy)-3-dodecene-1-ol

Base Information

Chemical Name:(Z)-12-(Tetrahydro-2H-pyran-2-yloxy)-3-dodecene-1-ol
CAS No.:69494-16-2
Molecular Formula:C17H32O3
Molecular Weight:284.439
Hs Code.:
Mol file:69494-16-2.mol

Synonyms:(Z)-12-(Tetrahydro-2H-pyran-2-yloxy)-3-dodecene-1-ol;(Z)-12-[(Tetrahydro-2H-pyran-2-yl)oxy]-3-dodecen-1-ol

Suppliers and Price of (Z)-12-(Tetrahydro-2H-pyran-2-yloxy)-3-dodecene-1-ol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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price

Total 3 raw suppliers

Chemical Property of (Z)-12-(Tetrahydro-2H-pyran-2-yloxy)-3-dodecene-1-ol

Chemical Property:

PSA：38.69000
LogP:4.19890

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

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Technology Process of (Z)-12-(Tetrahydro-2H-pyran-2-yloxy)-3-dodecene-1-ol

There total 8 articles about (Z)-12-(Tetrahydro-2H-pyran-2-yloxy)-3-dodecene-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 64031-52-3
12-(2-Tetrahydro-2H-pyran-2-yloxy)-3-dodecyn-1-ol

: 69494-16-2
12-(2-Tetrahydro-2H-pyran-2-yloxy)-3(Z)-dodecen-1-ol

Guidance literature:: With sodium tetrahydroborate; hydrogen; nickel diacetate; ethylenediamine; In ethanol; Ambient temperature;
DOI:10.1021/jo00106a037

Reference yield: 94.0%

: 303039-16-9
tert-butyl-dimethyl-[12-(tetrahydro-pyran-2-yloxy)-dodec-3-enyloxy]-silane

: 69494-16-2
12-(2-Tetrahydro-2H-pyran-2-yloxy)-3(Z)-dodecen-1-ol

Guidance literature:: With tetrabutyl ammonium fluoride; at 20 ℃; for 28h;
DOI:10.1016/S0040-4039(00)01064-9

Reference yield:

: 55362-80-6
9-bromononan-1-ol

: 69494-16-2
12-(2-Tetrahydro-2H-pyran-2-yloxy)-3(Z)-dodecen-1-ol

Guidance literature:: Multi-step reaction with 4 steps

1: 89 percent / PTSA / 2 h / 0 - 20 °C

2: 94 percent / acetonitrile / 38 h / 70 °C

3: 78 percent / LiHMDS / tetrahydrofuran; hexamethylphosphoric acid triamide / -78 - 20 °C

4: 94 percent / TBAF / 28 h / 20 °C

With tetrabutyl ammonium fluoride; toluene-4-sulfonic acid; lithium hexamethyldisilazane; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; acetonitrile; 1: acetalisation / 2: Substitution / 3: Wittig olefination / 4: Hydrolysis;
DOI:10.1016/S0040-4039(00)01064-9