5,10,15,20-TETRAKIS(4-CARBOXYMETHYLOXYPHENYL)-21H,23H-PORPHINE

Base Information

• Chemical Name: 5,10,15,20-TETRAKIS(4-CARBOXYMETHYLOXYPHENYL)-21H,23H-PORPHINE
• CAS No.: 127812-08-2
• Molecular Formula: C52H38N4O12
• Molecular Weight: 910.893
• Mol file: 127812-08-2.mol

Synonyms:5,10,15,20-TETRAKIS(4-CARBOXYMETHYLOXYPHENYL)-21H,23H-PORPHINE;Tetrakiscarboxymethyloxyphenylporphine;5,10,15,20-Tetrakis(4-carboxymethyloxyphenyl)porphyrin

Chemical Property of 5,10,15,20-TETRAKIS(4-CARBOXYMETHYLOXYPHENYL)-21H,23H-PORPHINE

Chemical Property:

• PSA: 242.42000
• Density: 1.443g/cm³
• LogP: 4.71980

Purity/Quality:

98%,99%, ^*data from raw suppliers

5,10,15,20-Tetrakis(4-carboxymethyloxyphenyl)porphyrin ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 5,10,15,20-Tetrakis(4-carboxymethyloxyphenyl)porphyrin (CAS# 127812-08-2) is a porphyrin dervative used in the preparation of catechol-functionalized zinc oxide nanorod/porphyrin assemblies. 5,10,15,20-Tetrakis(4-carboxymethyloxyphenyl)porphyrin has been used to form 109Pd-porphyrin complexes, coordination compound with anti-tumor properties.

Technology Process of 5,10,15,20-TETRAKIS(4-CARBOXYMETHYLOXYPHENYL)-21H,23H-PORPHINE

There total 12 articles about 5,10,15,20-TETRAKIS(4-CARBOXYMETHYLOXYPHENYL)-21H,23H-PORPHINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

C68H70N4O12 → 5,10,15,20-tetrakis(4-carboxymethyloxyphenyl)-21H,23H-porphine (127812-08-2)

Guidance literature:

With formic acid; at 25 ℃; for 18h;

DOI:10.1002/chem.201405039

Reference yield: 82.0%

5,10,15,20-tetra(4′-carboethoxymethyleneoxyphenyl)porphyrin (127812-10-6) → 5,10,15,20-tetrakis(4-carboxymethyloxyphenyl)-21H,23H-porphine (127812-08-2)

Guidance literature:

With potassium hydroxide; water; In ethanol; for 1h; Heating;

DOI:10.1007/BF00470694

Reference yield: 20.0%

meso-tetrakis<4-(allyloxy)phenyl>porphyrin (106456-81-9) → 5,10,15,20-tetrakis(4-carboxymethyloxyphenyl)-21H,23H-porphine (127812-08-2)

Guidance literature:

With pyridine; potassium permanganate; water; for 2h;

DOI:10.1007/BF00470694

upstream raw materials:

meso-tetrakis<4-(allyloxy)phenyl>porphyrin

5,10,15,20-tetra(4′-carboethoxymethyleneoxyphenyl)porphyrin

5,10,15,20-tetrakis(4'-hydroxyphenyl)porphyrin

chloroacetic acid

Refernces

• 1、 Guleria, Mohini,Kumar, Chandan,Das, Tapas,Amirdhanayagam, Jeyachitra,Sharma, Rohit,Sarma, Haladhar D.,Dash, Ashutosh. "Studies towards elucidating the potential of 5,10,15,20-tetrakis(: P -carboxy-methyleneoxyphenyl)porphyrin as a theranostic agent for applications in PET and PDT". . p. 657 - 666. Retrieved 2018.
• 2、 Karmakar, Anirban,Goldberg, Israel. "Flexible porphyrin tetracarboxylic acids for crystal engineering". . p. 4095 - 4100. Retrieved 2010.
• 3、 Burger, Alexandra,Costa, Rubén D.,Lobaz, Volodymyr,Peukert, Wolfgang,Guldi, Dirk M.,Hirsch, Andreas. "Layer-by-Layer Assemblies of Catechol-Functionalized TiO2 Nanoparticles and Porphyrins through Electrostatic Interactions". . p. 5041 - 5054. Retrieved 2015.