6-Bromo-1-nitronaphthalene

Base Information

• Chemical Name: 6-Bromo-1-nitronaphthalene
• CAS No.: 102153-48-0
• Molecular Formula: C10H6BrNO2
• Molecular Weight: 252.06414
• DSSTox Substance ID: DTXSID90356568
• Wikidata: Q82135977
• Mol file: 102153-48-0.mol

Synonyms:6-bromo-1-nitronaphthalene;102153-48-0;SCHEMBL5784407;Naphthalene, 6-bromo-1-nitro-;DTXSID90356568;MFCD01464122;AKOS016012711;DS-5465;FT-0703940;C71101;A896885

Chemical Property of 6-Bromo-1-nitronaphthalene

Chemical Property:

• Melting Point: 98-99 °C
• Boiling Point: 363.8±17.0 °C(Predicted)
• PSA: 45.82000
• Density: 1.662±0.06 g/cm3(Predicted)
• LogP: 4.03370
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 3.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 250.95819
• Heavy Atom Count: 14
• Complexity: 229

Purity/Quality:

98%min ^*data from raw suppliers

6-Bromo-1-nitronaphthalene 96% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC2=C(C=CC(=C2)Br)C(=C1)[N+](=O)[O-]
• Uses: 6-Bromo-1-nitronaphthalene (CAS#:102153-48-0) is a useful chemical reagent.

Technology Process of 6-Bromo-1-nitronaphthalene

There total 4 articles about 6-Bromo-1-nitronaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-amino-5-nitronaphthalene (607-44-3) → 6-bromo-1-nitro-naphthalene (102153-48-0)

Guidance literature:

With sulfuric acid; sodium nitrite; anschliessendes Behandeln mit CuBr und wss. HBr;

DOI:10.1039/jr9500000818

Reference yield:

2-bromo-5-nitro-[1]naphthylamine (90767-00-3) → 6-bromo-1-nitro-naphthalene (102153-48-0)

Guidance literature:

With sulfuric acid; acetic acid; Diazotization_.Erwaermen der Diazoniumsalz-Loesung mit Cu₂O und Aethanol auf 70grad;

DOI:10.1039/jr9420000723

Reference yield:

5-nitro-[1]naphthylamine (3272-91-1) → 6-bromo-1-nitro-naphthalene (102153-48-0)

Guidance literature:

Multi-step reaction with 2 steps

1: chloroform; bromine

2: concentrated H₂SO₄; glacial acetic acid / Diazotization_.Erwaermen der Diazoniumsalz-Loesung mit Cu₂O und Aethanol auf 70grad

With chloroform; sulfuric acid; bromine; acetic acid;

DOI:10.1039/jr9420000723

upstream raw materials:

2-amino-5-nitronaphthalene

2-bromo-5-nitro-[1]naphthylamine

5-nitro-[1]naphthylamine

Refernces