Potassium cyclobutyltrifluoroborate

Base Information

• Chemical Name: Potassium cyclobutyltrifluoroborate
• CAS No.: 1065010-88-9
• Molecular Formula: C4H7BF3K
• Molecular Weight: 162.004
• Mol file: 1065010-88-9.mol

Synonyms:Potassium cyclobutyltrifluoroborate;Potassium cyclobutyltrifluoroborate 97%;potassium cyclobutyltrifluoroboranuide

Chemical Property of Potassium cyclobutyltrifluoroborate

Chemical Property:

• Melting Point: 94-100°C
• PSA: 0.00000
• LogP: 2.38790

Purity/Quality:

98%,99%, ^*data from raw suppliers

PotassiumCyclobutyltrifluoroboranuide ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Potassium cyclobutyltrifluoroborate

There total 4 articles about Potassium cyclobutyltrifluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

cyclobutyl boronic acid (849052-26-2) → potassium cyclobutyltrifluoroboranuide (1065010-88-9)

Guidance literature:

cyclobutyl boronic acid; With potassium fluoride; In water; acetonitrile; at 21 ℃;

With L-Tartaric acid; In tetrahydrofuran; water; acetonitrile;

DOI:10.1002/anie.201203930

Reference yield: 40.0%

potassium hydrogen difluoride + tetrahydroxydiboron (13675-18-8) + 1,3-dioxoisoindolin-2-yl cyclobutanecarboxylate → potassium cyclobutyltrifluoroboranuide (1065010-88-9)

Guidance literature:

tetrahydroxydiboron; 1,3-dioxoisoindolin-2-yl cyclobutanecarboxylate; With (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; In N,N-dimethyl-formamide; for 12h; Inert atmosphere; Schlenk technique; Irradiation;

potassium hydrogen difluoride; In methanol; water; at 0 ℃; for 3h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.orglett.7b01181

Reference yield:

potassium hydrogen bifluoride + cyclobutyl boronic acid (849052-26-2) → potassium cyclobutyltrifluoroboranuide (1065010-88-9)

Guidance literature:

In methanol; at 0 ℃; for 0.5h; Inert atmosphere;

DOI:10.1021/acs.joc.6b02897

upstream raw materials:

cyclobutyl boronic acid

tetrahydroxydiboron

potassium hydrogenfluoride

2-cyclobutyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Downstream raw materials:

1-(4-cyclobutylphenyl)-1H-pyrrole

5-cyclobutyl-2-methoxypyridine

methyl 3-cyclobutylbenzoate

1-cyclobutyl-3,5-dimethoxybenzene