Hexacyclic endo,endo-dihydrodinorbornadiene

Base Information

• Chemical Name: Hexacyclic endo,endo-dihydrodinorbornadiene
• CAS No.: 64162-49-8
• Molecular Formula: C₁₄H₁₈
• Molecular Weight: 186.297
• Mol file: 64162-49-8.mol

Synonyms:Hexacyclic endo,endo-dihydrodinorbornadiene

Chemical Property of Hexacyclic endo,endo-dihydrodinorbornadiene

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of Hexacyclic endo,endo-dihydrodinorbornadiene

There total 5 articles about Hexacyclic endo,endo-dihydrodinorbornadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cobalt iodide dihydrate + bicyclo[2.2.1]hepta-2,5-diene (121-46-0) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → hexacyclo[9.2.1.02,10.03,8.04,6.05,9]-12-tetradecene + hexacyclo[9.2.1.02,10.03,8.04,6.05,9]tetradecane (51966-13-3,64162-49-8,66289-73-4,66289-74-5,96039-23-5)

Guidance literature:

With zinc; In 1,1-dichloroethane;

Reference yield:

norborn-2-ene (498-66-8) + quadricyclo[2.2.1.0.0]heptane (278-06-8) → bicyclo[2.2.1]hepta-2,5-diene (121-46-0) + C14H16 (7781-74-0,17926-98-6,17926-99-7,18067-61-3,33780-58-4) + C14H18 (51966-13-3,64162-49-8,66289-73-4,66289-74-5,96039-23-5) + C14H18 (51966-13-3,64162-49-8,66289-73-4,66289-74-5,96039-23-5)

Guidance literature:

With Pd₂(dba)(CHCl₃); triphenylphosphine; In benzene; at 20 ℃; for 5h; Yield given. Further byproducts given. Yields of byproduct given;

DOI:10.1007/BF00961046

Reference yield:

norborn-2-ene (498-66-8) + quadricyclo[2.2.1.0.0]heptane (278-06-8) → bicyclo[2.2.1]hepta-2,5-diene (121-46-0) + C14H16 (7781-74-0,17926-98-6,17926-99-7,18067-61-3,33780-58-4) + C14H18 (51966-13-3,64162-49-8,66289-73-4,66289-74-5,96039-23-5) + C14H18 (51966-13-3,64162-49-8,66289-73-4,66289-74-5,96039-23-5)

Guidance literature:

With Pd₂(dba)(CHCl₃); triphenylphosphine; In benzene; at 20 ℃; for 5h; Yield given. Further byproducts given. Yields of byproduct given;

DOI:10.1007/BF00961046

upstream raw materials:

norborn-2-ene

quadricyclo[2.2.1.0.0]heptane

bicyclo[2.2.1]hepta-2,5-diene

1,2-bis-(diphenylphosphino)ethane

Refernces

• 1、 Dzhemilev, U.M.,Khusnutdinov, R.I.,Dokichev, V.A.,Galeev, D.K.,Malikov, A.I.,et al.. "SYNTHESIS OF NEW TYPES STRAINED HYDROCARBONS BY CYCLOCODIMERIZATION OF QUADRICYCLE WITH NORBORNENES AND THEIR DERIVATIVES, CATALYZED BY PALLADIUM COMPLEXES". . p. 2247 - 2251. Retrieved 2007/10/02.