Glyceryl 1,3-dimyristate

Base Information

• Chemical Name: Glyceryl 1,3-dimyristate
• CAS No.: 7770-09-4
• Molecular Formula: C31H60O5
• Molecular Weight: 512.814
• European Community (EC) Number: 231-864-9
• NSC Number: 404226
• UNII: D8G6O94TLM
• DSSTox Substance ID: DTXSID30228331
• Nikkaji Number: J118.338I
• Wikidata: Q27276244
• Mol file: 7770-09-4.mol

Synonyms:1,2-dimyristoylglycerol;dimyristoyl diglyceride

Chemical Property of Glyceryl 1,3-dimyristate

Chemical Property:

• Vapor Pressure: 3.82E-16mmHg at 25°C
• Boiling Point: 585.4°Cat760mmHg
• Flash Point: 170°C
• PSA: 72.83000
• Density: 0.94g/cm³
• LogP: 8.83590
• Storage Temp.: −20°C
• XLogP3: 11.9
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 30
• Exact Mass: 512.44407501
• Heavy Atom Count: 36
• Complexity: 438

Purity/Quality:

99% ^*data from raw suppliers

1,3-Dimyristin ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCC)O

Technology Process of Glyceryl 1,3-dimyristate

There total 21 articles about Glyceryl 1,3-dimyristate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

vinyl myristate (5809-91-6) + glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0) → glycerol 1,3-dimyristate (7770-09-4)

Guidance literature:

With immobilized Candida antarctica lipase; In dichloromethane; at 0 - 4 ℃; for 5h;

DOI:10.1016/j.tet.2003.09.059

Reference yield: 90.0%

tetradecanoic acid 2-oxopropane-1,3-diyl ester (132333-70-1) → glycerol 1,3-dimyristate (7770-09-4)

Guidance literature:

With sodium cyanoborohydride; acetic acid; In tetrahydrofuran; for 0.5h;

DOI:10.1071/CH9902093

Reference yield: 87.0%

4-hydroxymethyl-1,3-dioxolan-2-one (931-40-8) + myristic anhydride (626-29-9) → glycerol 1,3-dimyristate (7770-09-4)

Guidance literature:

4-hydroxymethyl-1,3-dioxolan-2-one; myristic anhydride; at 80 ℃; for 7h;

With 1,4-diaza-bicyclo[2.2.2]octane; at 195 - 200 ℃; for 1.5h;

DOI:10.1007/s11746-012-2165-0

upstream raw materials:

1,3-Dichloro-2-propanol

potassium myristate

n-tetradecanoic acid

3-iodo-propane-1,2-diol

Downstream raw materials:

1.3-Di-O-myristoyl-glycerin-2-

1,2-dimyristoyl-rac-glycerol

C₄₃H₇₆ClO₇P