methyl 5-chloro-2-cyclopropoxybenzoate

Base Information

Chemical Name:methyl 5-chloro-2-cyclopropoxybenzoate
CAS No.:959749-02-1
Molecular Formula:C₁₁H₁₁ClO₃
Molecular Weight:226.66
Hs Code.:
Mol file:959749-02-1.mol

Synonyms:methyl 5-chloro-2-cyclopropoxybenzoate;METHYL 4-CHLORO-2-CYCLOPROPOXYBENZOATE

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 5-chloro-2-cyclopropoxybenzoate

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of methyl 5-chloro-2-cyclopropoxybenzoate

There total 4 articles about methyl 5-chloro-2-cyclopropoxybenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 959749-01-0
methyl 5-chloro-2-(vinyloxy)benzoate

: 959749-02-1
Methyl 5-chloro-2-cyclopropoxybenzoate

Guidance literature:: With diethylzinc; trifluoroacetic acid; In hexane; dichloromethane; at 0 - 25 ℃; for 8h;
DOI:10.1016/j.bmcl.2019.04.008

Reference yield:

: 593-71-5
Chloroiodomethane

: 959749-01-0
methyl 5-chloro-2-(vinyloxy)benzoate

: 959749-02-1
Methyl 5-chloro-2-cyclopropoxybenzoate

Guidance literature:: Chloroiodomethane; methyl 5-chloro-2-(vinyloxy)benzoate; In hexanes; 1,2-dichloro-ethane; at -5 - 20 ℃; for 1.75h;

With ammonia; water; ammonium chloride; In hexanes; 1,2-dichloro-ethane;

Reference yield:

: 959748-99-3
methyl 5-chloro-2-(2-chloroethoxy)benzoate

: 959749-02-1
Methyl 5-chloro-2-cyclopropoxybenzoate

Guidance literature:: Multi-step reaction with 2 steps

1: potassium tert-butylate / tetrahydrofuran / 0 °C

2: diethylzinc; trifluoroacetic acid / dichloromethane; hexane / 8 h / 0 - 25 °C

With potassium tert-butylate; diethylzinc; trifluoroacetic acid; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1016/j.bmcl.2019.04.008