m-bis(epoxyethyl)benzene

Base Information

• Chemical Name: m-bis(epoxyethyl)benzene
• CAS No.: 16832-59-0
• Molecular Formula: C10H10 O2
• Molecular Weight: 162.188
• Mol file: 16832-59-0.mol

Synonyms:Benzene,m-bis(epoxyethyl)- (6CI,8CI); m-Divinylbenzenediepoxide

Chemical Property of m-bis(epoxyethyl)benzene

Chemical Property:

• Vapor Pressure: 0.00396mmHg at 25°C
• Boiling Point: 288.8°Cat760mmHg
• Flash Point: 135.7°C
• PSA: 25.06000
• Density: 1.272g/cm³
• LogP: 1.82920

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of m-bis(epoxyethyl)benzene

There total 3 articles about m-bis(epoxyethyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,3-divinylbenzene (108-57-6) → 1,3-bis(oxiran-2-yl)benzene (16832-59-0) + m-Divinylbenzene monoepoxide (105430-20-4)

Guidance literature:

With dihydrogen peroxide; ammonium heptamolybdate; dioctyltin(IV) oxide; In chloroform; water; at 40 ℃; for 6h;

DOI:10.1246/bcsj.64.3442

Reference yield:

1,3-divinylbenzene (108-57-6) → 1,3-bis(oxiran-2-yl)benzene (16832-59-0)

Guidance literature:

With 3C₁₈H₁₆O₈^(2-)*3Cu⁽²⁺⁾; oxygen; pivalaldehyde; In acetonitrile; at 40 ℃; for 6h; under 760.051 Torr;

DOI:10.1002/ejic.201601242

Reference yield:

diazomethane (186581-53-3,908094-01-9,334-88-3) + Isophthalaldehyde (626-19-7) → 1,3-bis(oxiran-2-yl)benzene (16832-59-0)

Guidance literature:

With diethyl ether;

DOI:10.1002/hlca.19400230190

upstream raw materials:

diazomethane

Isophthalaldehyde

1,3-divinylbenzene

Downstream raw materials:

(R)-1-(3-((S)-oxiran-2-yl)phenyl)ethane-1,2-diol

(R)-1-(3-((R)-oxiran-2-yl)phenyl)ethane-1,2-diol

Refernces

• 1、 Inoue, Masami,Nakayama, Eiichi,Nakamura, Yuuko,Rengakuji, Seichi,Nishibe, Keiichi. "Effect of Anions on the Epoxidation of Styrenes with H2O2 in the presence of Ammonium Heptamolybdate(VI)-Dioctyltin Oxide catalysts". . p. 3442 - 3444. Retrieved 2007/10/02.