alpha-D-threo-Hex-3-enopyranoside, methyl 6-amino-3,4,6-trideoxy- (9CI)

Base Information

Chemical Name:alpha-D-threo-Hex-3-enopyranoside, methyl 6-amino-3,4,6-trideoxy- (9CI)
CAS No.:651302-67-9
Molecular Formula:C₇H₁₃NO₃
Molecular Weight:159.185
Hs Code.:
Mol file:651302-67-9.mol

Synonyms:alpha-D-threo-Hex-3-enopyranoside, methyl 6-amino-3,4,6-trideoxy- (9CI)

Suppliers and Price of alpha-D-threo-Hex-3-enopyranoside, methyl 6-amino-3,4,6-trideoxy- (9CI)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of alpha-D-threo-Hex-3-enopyranoside, methyl 6-amino-3,4,6-trideoxy- (9CI)

Chemical Property:

Purity/Quality:

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Technology Process of alpha-D-threo-Hex-3-enopyranoside, methyl 6-amino-3,4,6-trideoxy- (9CI)

There total 6 articles about alpha-D-threo-Hex-3-enopyranoside, methyl 6-amino-3,4,6-trideoxy- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 651302-49-7
methyl 2-O-benzoyl-3,4,6-trideoxy-6-azido-α-D-threo-hex-3-enopyranoside

: 651302-67-9
methyl 3,4,6-trideoxy-6-amino-α-D-threo-hex-3-enopyranoside

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; for 2.5h; Heating;
DOI:10.1081/CAR-120026469

Reference yield:

: 51385-38-7
(2S,3R,6S)-6-(hydroxymethyl)-2-methoxy-3,6-dihydro-2H-pyran-3-ol

: 651302-67-9
methyl 3,4,6-trideoxy-6-amino-α-D-threo-hex-3-enopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 73 percent / Et₃N / CH₂Cl₂ / 48 h / 0 - 20 °C

2: PPh₃; DEAD / tetrahydrofuran / 0 °C

3: 42 percent / NaN₃ / dimethylformamide / 2 h / 75 - 80 °C

4: 83 percent / LiAlH₄ / diethyl ether / 2.5 h / Heating

With lithium aluminium tetrahydride; sodium azide; triethylamine; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; diethyl ether; dichloromethane; N,N-dimethyl-formamide; 2: Mitsunobu reaction;
DOI:10.1081/CAR-120026469

Reference yield:

: 3366-47-0
2,3,4,6-tetra-O-acetyl-1,5-anhydro-D-arabinohex-1-enopyranose

: 651302-67-9
methyl 3,4,6-trideoxy-6-amino-α-D-threo-hex-3-enopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 43 percent / BF₃*Et₂O / toluene; methanol / 0.42 h

2: 61 percent / LiAlH₄ / tetrahydrofuran / 0.58 h / 0 °C

3: 73 percent / Et₃N / CH₂Cl₂ / 48 h / 0 - 20 °C

4: PPh₃; DEAD / tetrahydrofuran / 0 °C

5: 42 percent / NaN₃ / dimethylformamide / 2 h / 75 - 80 °C

6: 83 percent / LiAlH₄ / diethyl ether / 2.5 h / Heating

With lithium aluminium tetrahydride; sodium azide; boron trifluoride diethyl etherate; triethylamine; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide; toluene; 4: Mitsunobu reaction;
DOI:10.1081/CAR-120026469