O-n-Butanoyl-2,3,5,6-O-diisopropylidene-α-D-mannofuranoside

Base Information

• Chemical Name: O-n-Butanoyl-2,3,5,6-O-diisopropylidene-α-D-mannofuranoside
• CAS No.: 177562-07-1
• Molecular Formula: C₁₆H₂₆O₇
• Molecular Weight: 330.378
• Mol file: 177562-07-1.mol

Synonyms:O-n-Butanoyl-2,3,5,6-O-diisopropylidene-α-D-mannofuranoside

Chemical Property of O-n-Butanoyl-2,3,5,6-O-diisopropylidene-α-D-mannofuranoside

Chemical Property:

• PSA: 72.45000
• LogP: 1.72620
• Solubility.: Chloroform, Hexane

Purity/Quality:

98% ^*data from raw suppliers

O-n-Butanoyl-2,3,5,6-O-diisopropylidene-α-D-mannofuranoside ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of O-n-Butanoyl-2,3,5,6-O-diisopropylidene-α-D-mannofuranoside

There total 2 articles about O-n-Butanoyl-2,3,5,6-O-diisopropylidene-α-D-mannofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

butyryl chloride (141-75-3) + 2,3:5,6-di-O-isopropylidene-α-D-mannofuranose (14131-84-1) → 1-O-butanoyl-2,3:5,6-di-O-isopropylidene-α-D-mannofuranose (177562-07-1) + 1-O-butanoyl-2,3:5,6-di-O-isopropylidene-β-D-mannofuranose (177562-07-1)

Guidance literature:

With triethylamine; In toluene; Heating;

DOI:10.1016/S0968-0896(01)00285-1

Reference yield: 95.0%

butyryl chloride (141-75-3) + 2,3:5,6-di-O-isopropylidene-α-D-mannofuranose (14131-84-1) → 1-O-butanoyl-2,3:5,6-di-O-isopropylidene-α-D-mannofuranose (177562-07-1) + 1-O-butanoyl-2,3:5,6-di-O-isopropylidene-β-D-mannofuranose (177562-07-1)

Guidance literature:

With triethylamine; In toluene; Heating;

DOI:10.1016/S0968-0896(01)00285-1

Reference yield: 80.0%

1-O-butanoyl-2,3:5,6-di-O-isopropylidene-α-D-mannofuranose (177562-07-1) → 1-O-butanoyl-2,3-O-isopropylidene-α-D-mannofuranose (177562-15-1)

Guidance literature:

With CuCl₂*2H₂O; In ethanol; at 20 ℃; for 16h;

DOI:10.1016/S0968-0896(01)00285-1

upstream raw materials:

butyryl chloride

2,3:5,6-di-O-isopropylidene-α-D-mannofuranose

Downstream raw materials:

1-O-butanoyl-2,3-O-isopropylidene-α-D-mannofuranose

Refernces