(13R)-Labd-8(17)-ene-15,18-dioic acid dimethyl ester

Base Information

• Chemical Name: (13R)-Labd-8(17)-ene-15,18-dioic acid dimethyl ester
• CAS No.: 13346-06-0
• Molecular Formula: C₂₂H₃₆O₄
• Molecular Weight: 364.525
• Mol file: 13346-06-0.mol

Synonyms:(13R)-Labd-8(17)-ene-15,18-dioic acid dimethyl ester;(1S,βR,4aα,8aβ)-Decahydro-5α-(methoxycarbonyl)-β,5,8a-trimethyl-2-methylene-1-naphthalenepentanoic acid methyl ester

Chemical Property of (13R)-Labd-8(17)-ene-15,18-dioic acid dimethyl ester

Chemical Property:

• Boiling Point: 415.8±38.0 °C(Predicted)
• Density: 1.02±0.1 g/cm3(Predicted)

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (13R)-Labd-8(17)-ene-15,18-dioic acid dimethyl ester

There total 5 articles about (13R)-Labd-8(17)-ene-15,18-dioic acid dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

pinifolic acid (1412-99-3,4853-11-6,5956-15-0,13903-01-0,29455-26-3,33228-61-4,41787-69-3) → dimethyl pinifolate (1757-83-1,4586-33-8,13346-06-0,13902-83-5,29455-21-8,95784-00-2)

Guidance literature:

Multi-step reaction with 2 steps

1: methanol; diethyl ether / 0.25 h

2: methanol; diethyl ether / 0.25 h

In methanol; diethyl ether;

DOI:10.1016/S0031-9422(00)81114-0

Reference yield:

diazomethane (186581-53-3,908094-01-9,334-88-3) + 18-methyl pinifolate → dimethyl pinifolate (1757-83-1,4586-33-8,13346-06-0,13902-83-5,29455-21-8,95784-00-2)

Guidance literature:

In methanol; diethyl ether; for 0.25h;

DOI:10.1016/S0031-9422(00)81114-0

Reference yield:

→ dimethyl pinifolate (13346-06-0)

Guidance literature:

Pinifolinsaeure, Diazomethan, Ae.;

upstream raw materials:

diazomethane

pinifolic acid

Refernces