13-cis-Retinonitrile

Base Information

Chemical Name:13-cis-Retinonitrile
CAS No.:20638-89-5
Molecular Formula:C₂₀H₂₇N
Molecular Weight:281.441
Hs Code.:
Mol file:20638-89-5.mol

Synonyms:13-cis-Retinonitrile;(2E,4E,6E,8Z)-3,7-DiMethyl-9-(2,6,6-triMethyl-1-cyclohexen-1-yl)-2,4,6,8-nonatetraenenitrile

Suppliers and Price of 13-cis-Retinonitrile

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
13-cis-Retinonitrile
100mg
$ 1230.00

Total 2 raw suppliers

Chemical Property of 13-cis-Retinonitrile

Chemical Property:

PSA：23.79000
LogP:6.04158

Purity/Quality:

97% ^*data from raw suppliers

13-cis-Retinonitrile ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Uses An isomer of an all-trans-Retinal intermediate

Technology Process of 13-cis-Retinonitrile

There total 33 articles about 13-cis-Retinonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 1856-64-0
C₂₁H₂₇NO₂

: 20638-88-4,20638-89-5,20638-90-8,20638-91-9,56013-23-1,56085-51-9,56085-52-0,56142-98-4,76985-03-0,76985-04-1,119718-30-8,119718-31-9,137255-03-9,137255-04-0
3,7-Dimethyl-1-(2,6,6-trimethyl-cyclohexen-1-yl)-nonatetraen-1,3,5,7-saeure-9-nitril

Guidance literature:: With piperidine; pyridine; for 3h; Reflux;

Reference yield: 36.0%

: 110875-15-5
(4E,6E,8E)-3,7-dimethyl-3-hydroxy-9-(2,6,6-trimethyl-1-cyclohexenyl)-4,6,8-nonatrienenitrile

: 20638-88-4,20638-89-5,20638-90-8,20638-91-9,56013-23-1,56085-51-9,56085-52-0,56142-98-4,76985-03-0,76985-04-1,119718-30-8,119718-31-9,137255-03-9,137255-04-0
(4E,6E,8E)-3,7-dimethyl-9-(2,6,6-trimethylcyclohex-1-en-1-yl)nona-2,4,6,8-tetraenenitrile

Guidance literature:: With iodine; In benzene;

Reference yield:

: 54226-17-4
(2Z,4E)-3-methyl-5-[2,6,6-trimethylcyclohex-1-enyl]penta-2,4-dienal

: 20638-88-4,20638-89-5,20638-90-8,20638-91-9,56013-23-1,56085-51-9,56085-52-0,56142-98-4,76985-03-0,76985-04-1,119718-30-8,119718-31-9,137255-03-9,137255-04-0
(2E,4Z,6E,8E)-3,7-Dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraenenitrile

Guidance literature:: Multi-step reaction with 3 steps

1: Zn-PPh₃ / CH₂Cl₂ / Ambient temperature

2: 1.) n-BuLi / 1.) THF, -60 deg C, 2.) THF, -5 deg C

With n-butyllithium; triphenylphosphine; zinc; In dichloromethane;
DOI:10.1016/S0040-4039(00)79877-7