(αR)-α-[(2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl)oxy]benzeneacetamide

Base Information

Chemical Name:(αR)-α-[(2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl)oxy]benzeneacetamide
CAS No.:207512-68-3
Molecular Formula:C22H27NO11
Molecular Weight:481.456
Hs Code.:

Synonyms:(αR)-α-[(2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl)oxy]benzeneacetamide

Suppliers and Price of (αR)-α-[(2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl)oxy]benzeneacetamide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(αR)-α-[(2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl)oxy]benzeneacetamide
25mg
$ 120.00

Total 2 raw suppliers

Chemical Property of (αR)-α-[(2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl)oxy]benzeneacetamide

Chemical Property:

PSA：167.74000
LogP:1.46240
Solubility.:Chloroform, Dichloromethane

Purity/Quality:

97% ^*data from raw suppliers

(αR)-α-[(2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl)oxy]benzeneacetamide ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Uses (R)-Prunasin intermediate.

Technology Process of (αR)-α-[(2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl)oxy]benzeneacetamide

There total 1 articles about (αR)-α-[(2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl)oxy]benzeneacetamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 108-24-7
acetic anhydride

: 151649-54-6
(R)-α-(β-D-glucopyranosyloxy)phenylacetamide

: 207512-68-3
(R)-2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy(phenyl)acetamide

Guidance literature:: With pyridine; at 20 ℃; for 3h;
DOI:10.1080/07328303.2015.1105249

Reference yield: 97.0%

: 207512-68-3
(R)-2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy(phenyl)acetamide

: 60981-47-7
(2R)-2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy)phenylacetonitrile

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; triethylamine; In dichloromethane; at -78 ℃;
DOI:10.1016/S0040-4020(02)00304-6

Reference yield:

: 207512-68-3
(R)-2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy(phenyl)acetamide

: 99-18-3
prunasin

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) COCl)2, DMSO, 2.) Et₃N / 1.) CH₂Cl₂, -78 deg C, 10 min, 2.) -78 deg C, 15 min

2: 75 percent / LiBH₄ / diethyl ether; tetrahydrofuran / 14 h / Ambient temperature

With lithium borohydride; oxalyl dichloride; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; diethyl ether;
DOI:10.1271/bbb.62.453