(R)-Tol-Binap RuCl2 AMPY

Base Information

• Chemical Name: (R)-Tol-Binap RuCl2 AMPY
• CAS No.: 857678-55-8
• Molecular Formula: C₅₄H₄₈Cl₂N₂P₂Ru
• Molecular Weight: 958.912
• European Community (EC) Number: 812-843-9,813-215-7

Synonyms:(R)-Tol-Binap RuCl2 AMPY;858116-31-1;857678-55-8;(S)-Tol-Binap RuCl2 AMPY;Dichloro[(S)-(-)-2,2-bis(di-p-tolylphosphino)-1,1-binaphthyl](2-aminomethylpyridine)ruthenium(II);[1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane;dichlororuthenium;pyridin-2-ylmethanamine

Chemical Property of (R)-Tol-Binap RuCl2 AMPY

Chemical Property:

• PSA: 43.09000
• LogP: 11.42280
• Sensitive.: air sensitive
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 8
• Exact Mass: 958.171319
• Heavy Atom Count: 61
• Complexity: 963

Purity/Quality:

99% ^*data from raw suppliers

Dichloro[(S)-(-)-2,2-bis(di-p-tolylphosphino)-1,1-binaphthyl](2-aminomethylpyridine)ruthenium(II) RuCl2(AMPY)[(S)-Tol-Binap] ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=C(C=C7)C)C8=CC=C(C=C8)C.C1=CC=NC(=C1)CN.Cl[Ru]Cl

Technology Process of (R)-Tol-Binap RuCl2 AMPY

There total 2 articles about (R)-Tol-Binap RuCl2 AMPY which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-(Aminomethyl)pyridine (3731-51-9) + [RuCl2[(S)-2,2'-bis(di-4-tolylphosphino)-1,1'-binaphthyl](dimethylformamide)(n) → [dichloro((S)-2,2'-bis(di-4-tolylphosphino)-1,1'-binaphthyl)(α-picolylamino)ruthenium(II)] (857678-55-8,858116-31-1,868671-38-9)

Guidance literature:

In dichloromethane; a Ru compd. treated with amine (1.2 equiv.) at 25°C for 2 h;

DOI:10.1021/ja052071+

Reference yield:

→ [dichloro((S)-2,2'-bis(di-4-tolylphosphino)-1,1'-binaphthyl)(α-picolylamino)ruthenium(II)] (857678-55-8,858116-31-1,868671-38-9)

Guidance literature:

Reference yield:

sodium tetrahydroborate (16940-66-2) + [dichloro((S)-2,2'-bis(di-4-tolylphosphino)-1,1'-binaphthyl)(α-picolylamino)ruthenium(II)] (857678-55-8,858116-31-1,868671-38-9) → [hydrido((S)-2,2'-bis(di-4-tolylphosphino)-1,1'-binaphthyl)(α-picolylamino)(.etha.-1-tetrahydroborato)ruthenium(II)] (857678-56-9)

Guidance literature:

In ethanol; benzene; 16 equiv. of B compd.;

DOI:10.1021/ja052071+

upstream raw materials:

2-(Aminomethyl)pyridine

Downstream raw materials:

[hydrido((S)-2,2'-bis(di-4-tolylphosphino)-1,1'-binaphthyl)(α-picolylamino)(.etha.-1-tetrahydroborato)ruthenium(II)]

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