Cis-4-Cyclohexylcyclohexanol

Base Information

• Chemical Name: Cis-4-Cyclohexylcyclohexanol
• CAS No.: 7335-11-7
• Molecular Formula: C12H22O
• Molecular Weight: 182.306
• Mol file: 7335-11-7.mol

Synonyms:Cis-4-Cyclohexylcyclohexanol

Chemical Property of Cis-4-Cyclohexylcyclohexanol

Chemical Property:

• Melting Point: 92-93 °C
• Boiling Point: 283.9±8.0 °C(Predicted)
• PKA: 15.31±0.40(Predicted)
• PSA: 20.23000
• Density: 0.993±0.06 g/cm3(Predicted)
• LogP: 3.11780
• Storage Temp.: 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

cis-[1,1'-Bi(cyclohexan)]-4-ol 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cis-4-Cyclohexylcyclohexanol

There total 15 articles about Cis-4-Cyclohexylcyclohexanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 11.0%

4-Phenylphenol (92-69-3) → trans-4-phenylcyclohexanol (5437-46-7,7335-12-8,5769-13-1) + cis-4-phenylcyclohexanol (7335-12-8) + trans-4-cyclohexylcyclohexanol (7335-42-4) + cis-4-cyclohexylcyclohexanol (7335-11-7) + p-cyclohexylphenol (1131-60-8)

Guidance literature:

With hydrogen; nickel; In ethanol; at 50 ℃; for 5h; under 3677.5 Torr; Product distribution; Rate constant; other biphenyls; other solvent, other catalysts;

DOI:10.1021/jo00385a018

Reference yield:

4-Phenylphenol (92-69-3) → cis-4-cyclohexylcyclohexanol (7335-11-7)

Guidance literature:

With hydrogen; rhodium on alumina; In acetic acid;

DOI:10.1021/jo00965a028

Reference yield:

4-Phenylphenol (92-69-3) → trans-4-cyclohexylcyclohexanol (7335-42-4) + cis-4-cyclohexylcyclohexanol (7335-11-7)

Guidance literature:

With hydrogen; In cyclohexane; at 99.84 ℃; for 1h; under 15001.5 Torr; Solvent; regioselective reaction; Autoclave; Sealed tube;

DOI:10.1007/s10562-012-0906-1

upstream raw materials:

4-cyclohexylcyclohexanone

4-Phenylphenol

trans-4-cyclohexylcyclohexanol

1,1-bis(p-hydroxyphenyl)cyclohexane

Downstream raw materials:

4-cyclohexylcyclohexanone

cyclohexylcyclohexane

Refernces

• 1、 Liu, Chengyun,Lu, Lianhai,Rong, Zeming,Liang, Changhai,Wang, Yue,Qu, Qingping. "Carbon supported Pd nanocrystals as high efficient catalyst for regioselective hydrogenation of p-phenylphenol to p-cyclohexylphenol". . p. 1321 - 1329. Retrieved 2013/01/15.