3,4-a']dinaphthalen-4-yl)[(1R)-1-phenylethyl]-aMine

Base Information

• Chemical Name: 3,4-a']dinaphthalen-4-yl)[(1R)-1-phenylethyl]-aMine
• CAS No.: 934705-43-8
• Molecular Formula: C₂₈H₂₂NO₂P
• Molecular Weight: 435.462
• Mol file: 934705-43-8.mol

Synonyms:3,4-a']dinaphthalen-4-yl)[(R)-1-phenylethyl]amine;(11bR)-N-[(R)-1-Phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3, 2]dioxaphosphepin-4-amine

Chemical Property of 3,4-a']dinaphthalen-4-yl)[(1R)-1-phenylethyl]-aMine

Chemical Property:

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,4-a']dinaphthalen-4-yl)[(1R)-1-phenylethyl]-aMine

There total 10 articles about 3,4-a']dinaphthalen-4-yl)[(1R)-1-phenylethyl]-aMine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

(R)-1-phenyl-ethyl-amine (3886-69-9) + (S)-N,N-dimethyldinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine → (3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)-(1-phenyl-ethyl)-amine (422509-53-3,556808-28-7,934705-43-8,556808-29-8)

Guidance literature:

With 1H-tetrazole; In toluene; Heating;

DOI:10.1021/ol027457t

Reference yield: 69.0%

(S)-1-phenyl-ethylamine (2627-86-3) + (R)-1,1'-Bi-2-naphthol (18531-94-7) → (3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)-(1-phenyl-ethyl)-amine (422509-53-3,556808-28-7,934705-43-8,556808-29-8)

Guidance literature:

(R)-1,1'-Bi-2-naphthol; With triethylamine; phosphorus trichloride; In toluene; at 20 ℃; for 6h;

(S)-1-phenyl-ethylamine; With triethylamine; In toluene; at 20 ℃; for 18h; Further stages.;

DOI:10.1002/ejoc.200390162

Reference yield: 35.0%

(S)-1-phenyl-ethylamine (2627-86-3) + (S)-[1,1']-binaphthalenyl-2,2'-diol (18531-99-2) → (3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)-(1-phenyl-ethyl)-amine (422509-53-3,556808-28-7,934705-43-8,556808-29-8)

Guidance literature:

(S)-[1,1']-binaphthalenyl-2,2'-diol; With triethylamine; phosphorus trichloride; In toluene; at 20 ℃; for 6h;

(S)-1-phenyl-ethylamine; With triethylamine; In toluene; at 20 ℃; for 18h; Further stages.;

DOI:10.1002/ejoc.200390162

upstream raw materials:

rac-methylbenzylamine

(R)-1-phenyl-ethyl-amine

(S)-1-phenyl-ethylamine

(S)-[1,1']-binaphthalenyl-2,2'-diol