monoacetoxyscirpenol

Base Information

• Chemical Name: monoacetoxyscirpenol
• CAS No.: 96699-75-1
• Molecular Formula: C₁₇H₂₄O₆
• Molecular Weight: 324.374
• Mol file: 96699-75-1.mol

Synonyms:PubChem ID: 114922

Chemical Property of monoacetoxyscirpenol

Chemical Property:

• Vapor Pressure: 2.1E-10mmHg at 25°C
• Boiling Point: 460.2°C at 760 mmHg
• Flash Point: 165°C
• Density: 1.34g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of monoacetoxyscirpenol

There total 8 articles about monoacetoxyscirpenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

C22H32O7 (97350-75-9,97350-77-1,121471-17-8) → 4-β-acetoxyscirpene-3α,15-diol (2531-11-5,174421-34-2,96699-75-1)

Guidance literature:

With acetic acid; In tetrahydrofuran; for 120h; Ambient temperature;

DOI:10.1021/jo00217a046

Reference yield:

C20H30O6 (77620-41-8,97372-96-8,97413-89-3,106454-34-6) → 4-β-acetoxyscirpene-3α,15-diol (2531-11-5,174421-34-2,96699-75-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 58 percent / DBU / benzene / 6 h / Ambient temperature

2: 90 percent / aq. AcOH / tetrahydrofuran / 120 h / Ambient temperature

With acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; benzene;

DOI:10.1021/jo00217a046

Reference yield:

C24H34O8 (77620-40-7,97372-95-7,97413-94-0,106454-35-7) → 4-β-acetoxyscirpene-3α,15-diol (2531-11-5,174421-34-2,96699-75-1)

Guidance literature:

Multi-step reaction with 3 steps

1: aq. NaOH / tetrahydrofuran; methanol

2: 58 percent / DBU / benzene / 6 h / Ambient temperature

3: 90 percent / aq. AcOH / tetrahydrofuran / 120 h / Ambient temperature

With sodium hydroxide; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; methanol; benzene;

DOI:10.1021/jo00217a046

upstream raw materials:

C₂₂H₃₂O₇

C₂₀H₂₉BrO₆

C₂₀H₃₀O₆

C₂₂H₃₁BrO₇