(5aR,7aα,11bα)-Dodecahydro-5aβ,8,8,11aβ-tetramethylnaphtho[2,1-d][1,3]dioxepin

Base Information

Chemical Name:(5aR,7aα,11bα)-Dodecahydro-5aβ,8,8,11aβ-tetramethylnaphtho[2,1-d][1,3]dioxepin
CAS No.:38419-77-1
Molecular Formula:C17H30O2
Molecular Weight:266.424
Hs Code.:
Mol file:38419-77-1.mol

Synonyms:(5aR,7aα,11bα)-Dodecahydro-5aβ,8,8,11aβ-tetramethylnaphtho[2,1-d][1,3]dioxepin

Suppliers and Price of (5aR,7aα,11bα)-Dodecahydro-5aβ,8,8,11aβ-tetramethylnaphtho[2,1-d][1,3]dioxepin

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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Total 3 raw suppliers

Chemical Property of (5aR,7aα,11bα)-Dodecahydro-5aβ,8,8,11aβ-tetramethylnaphtho[2,1-d][1,3]dioxepin

Chemical Property:

PSA：18.46000
LogP:4.38210

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (5aR,7aα,11bα)-Dodecahydro-5aβ,8,8,11aβ-tetramethylnaphtho[2,1-d][1,3]dioxepin

There total 7 articles about (5aR,7aα,11bα)-Dodecahydro-5aβ,8,8,11aβ-tetramethylnaphtho[2,1-d][1,3]dioxepin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 75-11-6
diiodomethane

: 38419-75-9
(1R,2R,4aS,8aS)-1-(2-hydroxyethyl)-2,5,5,8a-tetramethyl-decahydronaphthalen-2-ol

: 38419-77-1
(4aS,6aR,11aR,11bS)-4,4,6a,11b-Tetramethyl-dodecahydro-7,9-dioxa-cyclohepta[a]naphthalene

Guidance literature:: In toluene; for 4h; Heating;

Reference yield:

: 515-03-7
sclareol

: 38419-77-1
(4aS,6aR,11aR,11bS)-4,4,6a,11b-Tetramethyl-dodecahydro-7,9-dioxa-cyclohepta[a]naphthalene

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) ruthenium chloride trihydrate, sodium periodate; 2.) lithium aluminum hydride / 1.) CCl₄, CH₃CN, H₂O, 45 deg C to rt; 2.) ether, 0 deg C, 1 h

2: 60 percent / toluene / 4 h / Heating

With ruthenium trichloride; sodium periodate; lithium aluminium tetrahydride; In toluene;

Reference yield:

: 5153-92-4
sclareol oxide

: 38419-77-1
(4aS,6aR,11aR,11bS)-4,4,6a,11b-Tetramethyl-dodecahydro-7,9-dioxa-cyclohepta[a]naphthalene

Guidance literature:: Multi-step reaction with 3 steps

1: 90 percent / O₃ / CH₂Cl₂; methanol

2: LiAlH₄ / tetrahydrofuran / Ambient temperature

3: 60 percent / toluene / 4 h / Heating

With lithium aluminium tetrahydride; ozone; In tetrahydrofuran; methanol; dichloromethane; toluene;