4-Isopropyl-6-methylene-3,4,4a,5,6,7,8,8a-octahydro-1(2H)-naphthalenone

Base Information

Chemical Name:4-Isopropyl-6-methylene-3,4,4a,5,6,7,8,8a-octahydro-1(2H)-naphthalenone
CAS No.:82096-16-0
Molecular Formula:C₁₄H₂₂O
Molecular Weight:206.328
Hs Code.:
DSSTox Substance ID:DTXSID10702381
Nikkaji Number:J46.979C
Mol file:82096-16-0.mol

Synonyms:82096-16-0;4-Isopropyl-6-methylene-3,4,4a,5,6,7,8,8a-octahydro-1(2H)-naphthalenone;DTXSID10702381;6-Methylidene-4-(propan-2-yl)octahydronaphthalen-1(2H)-one

Suppliers and Price of 4-Isopropyl-6-methylene-3,4,4a,5,6,7,8,8a-octahydro-1(2H)-naphthalenone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 4-Isopropyl-6-methylene-3,4,4a,5,6,7,8,8a-octahydro-1(2H)-naphthalenone

Chemical Property:

PSA：17.07000
LogP:3.59400
XLogP3:3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:206.167065321
Heavy Atom Count:15
Complexity:277

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)C1CCC(=O)C2C1CC(=C)CC2

Technology Process of 4-Isopropyl-6-methylene-3,4,4a,5,6,7,8,8a-octahydro-1(2H)-naphthalenone

There total 2 articles about 4-Isopropyl-6-methylene-3,4,4a,5,6,7,8,8a-octahydro-1(2H)-naphthalenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 8.0%

: 82096-11-5,86361-43-5
(4S,4aS,8aS)-4-Isopropyl-6-trimethylsilanylmethyl-3,4,4a,5,8,8a-hexahydro-2H-naphthalen-1-one

: 29292-32-8,39765-64-5,82166-08-3,86391-43-7,94841-67-5,98975-20-3,99031-91-1
(4R,4aR,8aR)-4-Isopropyl-6-methyl-3,4,4a,5,8,8a-hexahydro-2H-naphthalen-1-one

: 82096-16-0,86361-45-7
(4R,4aR,8aR)-4-Isopropyl-6-methylene-octahydro-naphthalen-1-one

Guidance literature:: With cesium fluoride; In dimethyl sulfoxide; at 100 ℃; for 1h; Title compound not separated from byproducts;
DOI:10.1016/S0040-4020(01)88587-2

Reference yield:

: 2158-59-0,2158-61-4,100295-52-1,500-02-7
cryptone

: 82096-16-0,86361-45-7
(4R,4aR,8aR)-4-Isopropyl-6-methylene-octahydro-naphthalen-1-one

Guidance literature:: Multi-step reaction with 2 steps

1: aluminium trichloride / benzene / 13 h / 60 °C

2: 8 percent / CsF / dimethylsulfoxide / 1 h / 100 °C

With aluminium trichloride; cesium fluoride; In dimethyl sulfoxide; benzene;
DOI:10.1016/S0040-4020(01)88587-2