Bicyclo[7.1.0]decane

Base Information

• Chemical Name: Bicyclo[7.1.0]decane
• CAS No.: 286-76-0
• Molecular Formula: C₁₀H₁₈
• Molecular Weight: 138.253
• Mol file: 286-76-0.mol

Synonyms:Bicyclo[7.1.0]decane

Chemical Property of Bicyclo[7.1.0]decane

Chemical Property:

• PSA: 0.00000
• LogP: 3.36680

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Bicyclo[7.1.0]decane

There total 5 articles about Bicyclo[7.1.0]decane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trans-tricyclo<7.1.0.04,6>deca-2,7-diene → cyclodecane (293-96-9) + bicyclo<7.1.0>decane (286-76-0,66537-41-5) + trans-tricyclo<7.1.0.04,6>decane (286-73-7,89955-58-8,89955-59-9)

Guidance literature:

With hydrogen; nickel; In hexane; at 60 ℃; for 1h; under 60800 Torr; Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1007/BF00952847

Reference yield:

(E)-(S)-10,10-Dibromo-bicyclo[7.1.0]dec-1-ene (7056-79-3) → (+)-trans-Bicyclo<7.1.0>decan (286-76-0,13758-98-0,66537-41-5)

Guidance literature:

With ammonia; sodium; tert-butyl alcohol; In diethyl ether;

DOI:10.1021/ja00748a059

Reference yield:

cyclonona-1,2-diene (1123-11-1) → (+)-trans-Bicyclo<7.1.0>decan (286-76-0,13758-98-0,66537-41-5)

Guidance literature:

Multi-step reaction with 2 steps

2: Na, liq. NH₃, tBuOH / diethyl ether

With ammonia; sodium; tert-butyl alcohol; In diethyl ether;

DOI:10.1021/ja00748a059

upstream raw materials:

Bicyclo[7.1.0]decadien-(3,6)

(E)-(S)-10,10-Dibromo-bicyclo[7.1.0]dec-1-ene

cyclonona-1,2-diene