SEC-BUTYLCYCLOPROPANE

Base Information

• Chemical Name: SEC-BUTYLCYCLOPROPANE
• CAS No.: 5750-02-7
• Molecular Formula: C₇H₁₄
• Molecular Weight: 98.1882
• Mol file: 5750-02-7.mol

Synonyms:Butane,2-cyclopropyl- (6CI,7CI,8CI); NSC 23693; sec-Butylcyclopropane

Chemical Property of SEC-BUTYLCYCLOPROPANE

Chemical Property:

• Vapor Pressure: 54.4mmHg at 25°C
• Boiling Point: 94.3°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 0.805g/cm³
• LogP: 2.44250

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of SEC-BUTYLCYCLOPROPANE

There total 4 articles about SEC-BUTYLCYCLOPROPANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1,1-dibromodispiro<2.2.1>heptane (139540-20-8) → (1-methyl-propyl)cyclopropane (5750-02-7) + dispiro[2.0.24.13]heptane (33475-22-8) + 1-methyl-1-cyclopropylcyclopropane (61975-75-5)

Guidance literature:

With lithium; tert-butyl alcohol; In tetrahydrofuran; for 3h;

Reference yield: 60.0%

1,1-Dichloro-dispiro[2.0.2.1]heptane (139540-19-5) → (1-methyl-propyl)cyclopropane (5750-02-7) + dispiro[2.0.24.13]heptane (33475-22-8) + 1-methyl-1-cyclopropylcyclopropane (61975-75-5)

Guidance literature:

With lithium; tert-butyl alcohol; In tetrahydrofuran; for 3h;

Reference yield:

2-cyclopropyl-1-butene (5809-54-1) → (1-methyl-propyl)cyclopropane (5750-02-7)

Guidance literature:

With ethanol; copper oxide-chromium oxide; barium(II) oxide; at 100 - 130 ℃; under 80905.8 Torr; Hydrogenation;

DOI:10.1021/ja01135a051

upstream raw materials:

2-cyclopropyl-1-butene

3-methyl-1-pentene

bis(iodomethyl)zinc

1,1-Dichloro-dispiro[2.0.2.1]heptane