(η5-2,4-Cyclopentadien-1-yl)[(1,2,3-η)-1-phenyl-2-propenyl]-palladium 95%

Base Information

• Chemical Name: (η5-2,4-Cyclopentadien-1-yl)[(1,2,3-η)-1-phenyl-2-propenyl]-palladium 95%
• CAS No.: 105333-10-6
• Molecular Formula: C14H14Pd
• Molecular Weight: 288.685
• Mol file: 105333-10-6.mol

Synonyms:(η5-2,4-Cyclopentadien-1-yl)[(1,2,3-η)-1-phenyl-2-propenyl]-palladium 95%;(η5-2,4-Cyclopentadien-1-yl)[(1,2,3-η)-1-phenyl-2-propenyl]-palladiuM,95%;(2,4-Cyclopentadien-1-yl)(phenyl-2-propenyl)-palladium;Cyclopentadienyl[(1,2,3-n)-1-phenyl-2-propenyl]palladiuM(II), 98%;(η5-2,4-Cyclopentadien-1-yl)[(1,2,3-η)-1-phenyl-2-propenyl]-palladium ;(eta5-2,4-Cyclopentadien-1-yl)[(1,2,3-eta)-1-phenyl-2-propenyl]-palladium 95%

Chemical Property of (η5-2,4-Cyclopentadien-1-yl)[(1,2,3-η)-1-phenyl-2-propenyl]-palladium 95%

Chemical Property:

• Melting Point: 45-47°C
• Flash Point: 47℃
• PSA: 0.00000
• LogP: 2.03850
• Storage Temp.: 2-8°C
• Sensitive.: air sensitive, store cold

Purity/Quality:

98%,99%, ^*data from raw suppliers

Cyclopentadienyl[(1,2,3-n)-1-phenyl-2-propenyl]palladium(II), 98% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F
• Statements: 11

MSDS Files:

SDS file from LookChem

Useful:

• Uses: A superior precursor for the preparation of palladium(0)-based cross-coupling and other catalytic reactions.

Technology Process of (η5-2,4-Cyclopentadien-1-yl)[(1,2,3-η)-1-phenyl-2-propenyl]-palladium 95%

There total 3 articles about (η5-2,4-Cyclopentadien-1-yl)[(1,2,3-η)-1-phenyl-2-propenyl]-palladium 95% which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

cinnamylpalladium(II) chloride + sodium cyclopentadienide → η5‐cyclopentadienyl‐η3‐1‐phenylallylpalladium (105333-10-6)

Guidance literature:

In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1021/ol5028333

Reference yield: 84.0%

bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)] + sodium cyclopentadienide → η5‐cyclopentadienyl‐η3‐1‐phenylallylpalladium (105333-10-6)

Guidance literature:

In tetrahydrofuran; (Ar or N2); using Schlenk techniques; addn. dropwise soln. of NaCp in THF to soln. of (Pd(PhC3H4)Cl)2 in THF at -78°C, stirring for 5 min, warming to room temp.; placing in an ice bath, removal of solvent from cooled soln. under reduced pressure, extn. using 3 portions of hexanes, concn. under vac., dissolving in min amts. of hexanes, crystn. at -40°C;

DOI:10.1021/om300154m

Reference yield: 73.0%

bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)] → η5‐cyclopentadienyl‐η3‐1‐phenylallylpalladium (105333-10-6)

Guidance literature:

With C₅H₅Na; In tetrahydrofuran; under N2, Schlenk techniques; according to S. D. Robinson and B. L. Shaw, J. Chem. Soc., (1963) 4806; mixing of THF soln. of Pd-complex and NaC5H5, stirred (10 min); evapn., extn. (hexane), cooling (-30°C); elem. anal.;

DOI:10.1016/0022-328X(86)82060-5

Downstream raw materials:

palladium

bis-[1,3-(diphenylphosphino)propane]palladium⁽⁰⁾

[Pd(dba)(dppp)]

bis(tri-t-butylphosphine)palladium⁽⁰⁾

Refernces

• 1、 Vita, Maria Victoria,Mieville, Pascal,Waser, Jerome. "Enantioselective synthesis of polycyclic carbocycles via an alkynylation-allylation-cyclization strategy". . p. 5768 - 5771. Retrieved 2014.
• 2、 Murrall, Nicholas W.,Welch, Alan J.. "ASYMMETRICALLY BONDED ? LIGANDS I. HINGING AWAY FROM METAL OF SUBSTITUTED ALLYLS: SYNTHESES OF 1-syn-METHYL AND -PHENYL COMPLEXES, AND THE MOLECULAR STRUCTURES OF ((η-1-Ph-C3H4)Pd(tmeda))BF4, ((η-C5H5)Pd(η-1-Ph-C3H4)), AND ((phen)Mo(CO)2(NCS)(η-1-Ph-C3H4)) AT 185 K". . p. 109 - 130. Retrieved 2007/10/02.