10-UNDECENYLDIMETHYLCHLOROSILANE

Base Information

• Chemical Name: 10-UNDECENYLDIMETHYLCHLOROSILANE
• CAS No.: 18406-97-8
• Molecular Formula: C13H27ClSi
• Molecular Weight: 246.896
• Hs Code.: 2931900090
• Mol file: 18406-97-8.mol

Synonyms:10-UNDECENYLDIMETHYLCHLOROSILANE

Chemical Property of 10-UNDECENYLDIMETHYLCHLOROSILANE

Chemical Property:

• Vapor Pressure: 0.007mmHg at 25°C
• Melting Point: <0°C
• Boiling Point: 100°C 2mm
• Flash Point: >100°C
• PSA: 0.00000
• Density: 0,87 g/cm3
• LogP: 5.73710

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Statements: 34
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 10-UNDECENYLDIMETHYLCHLOROSILANE

There total 2 articles about 10-UNDECENYLDIMETHYLCHLOROSILANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

1-undecen-11-ylbromide (7766-50-9) + dimethylsilicon dichloride (75-78-5,30107-43-8) → chlorodimethyl(undec-10-enyl)silane (18406-97-8)

Guidance literature:

1-undecen-11-ylbromide; With iodine; magnesium; In diethyl ether; at 20 ℃; Inert atmosphere; Reflux;

dimethylsilicon dichloride; In tetrahydrofuran; diethyl ether; at 20 ℃; Inert atmosphere;

DOI:10.1002/ejoc.201101320

Reference yield:

ethylmagnesium bromide (925-90-6) → chlorodimethyl(undec-10-enyl)silane (18406-97-8)

Guidance literature:

With diethyl ether; anschliessend Behandeln mit Chlor-dimethyl-silan;

DOI:10.1021/jo50011a024

Reference yield:

chlorodimethyl(undec-10-enyl)silane (18406-97-8) → 12-(dimethyl-phenethyl-silanyl)-dodecanoic acid (6812-53-9)

Guidance literature:

Multi-step reaction with 2 steps

2: HBr; dibenzoyl peroxide / anschliessendes Behandeln mit Magnesium und CO₂

With hydrogen bromide; dibenzoyl peroxide;

DOI:10.1021/jo50011a024

upstream raw materials:

ethylmagnesium bromide

1-undecen-11-ylbromide

dimethylsilicon dichloride

Downstream raw materials:

12-(dimethyl-phenethyl-silanyl)-dodecanoic acid

Refernces