6-BroMo-2-benzothiazolecarboxylic acid ethyl ester

Base Information

Chemical Name:6-BroMo-2-benzothiazolecarboxylic acid ethyl ester
CAS No.:1188024-51-2
Molecular Formula:C10H8BrNO2S
Molecular Weight:286.149
Hs Code.:2934200090
Mol file:1188024-51-2.mol

Synonyms:6-BroMo-2-benzothiazolecarboxylic acid ethyl ester;ethyl 6-bromobenzo[d]thiazole-2-carboxylate

Suppliers and Price of 6-BroMo-2-benzothiazolecarboxylic acid ethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
Ethyl6-bromobenzo[d]thiazole-2-carboxylate 95+%
1g
$ 545.00

Alichem
Ethyl6-bromobenzo[d]thiazole-2-carboxylate
1g
$ 556.38

Total 3 raw suppliers

Chemical Property of 6-BroMo-2-benzothiazolecarboxylic acid ethyl ester

Chemical Property:

Boiling Point:366.1±34.0 °C(Predicted)
PKA:-1.71±0.10(Predicted)
PSA：67.43000
Density:1.618±0.06 g/cm3(Predicted)
LogP:3.23550

Purity/Quality:

98%min ^*data from raw suppliers

Ethyl6-bromobenzo[d]thiazole-2-carboxylate 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 6-BroMo-2-benzothiazolecarboxylic acid ethyl ester

There total 2 articles about 6-BroMo-2-benzothiazolecarboxylic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 1202252-00-3
C₁₈H₁₈BrNO₄S

: 321-23-3
4-bromo-2-fluoronitrobenzene

: 1188024-51-2
6-bromobenzothiazole-2-carboxylic acid ethyl ester

: 1202251-94-2
4-bromo-2-(4-methoxybenzylsulfanyl)-1-nitrobenzene

Guidance literature:: C₁₈H₁₈BrNO₄S; 4-bromo-2-fluoronitrobenzene; With thiourea; trifluoroacetic acid; Green chemistry;

With sodium hydroxide; Green chemistry;
DOI:10.1016/j.tetlet.2015.02.054

Reference yield:

: 321-23-3
4-bromo-2-fluoronitrobenzene

: 1188024-51-2
6-bromobenzothiazole-2-carboxylic acid ethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1.1: trifluoroacetic acid; thiourea / 80 °C

1.2: 6 h / 50 °C

2.1: tin(II) chloride dihdyrate / ethyl acetate / 20 °C

3.1: pyridine / dichloromethane

4.1: trifluoroacetic acid; thiourea / Green chemistry

4.2: Green chemistry

With pyridine; tin(II) chloride dihdyrate; thiourea; trifluoroacetic acid; In dichloromethane; ethyl acetate;
DOI:10.1016/j.tetlet.2015.02.054

Reference yield:

: 1188024-51-2
6-bromobenzothiazole-2-carboxylic acid ethyl ester

: 1765-93-1
4-fluoroboronic acid

: C₁₆H₁₂FNO₂S

Guidance literature:: With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium carbonate; In ethanol; water; toluene; at 100 ℃;
DOI:10.3390/antibiotics11010030