(R,R)-(-)-[NBDRHDIPHOS] HEXAFLUOROPHOSPHATE, COMPLEX WITH ACETONE

Base Information

• Chemical Name: (R,R)-(-)-[NBDRHDIPHOS] HEXAFLUOROPHOSPHATE, COMPLEX WITH ACETONE
• CAS No.: 100945-97-9
• Molecular Formula: C33H40F6O2P3Rh?
• Molecular Weight: 0
• Mol file: 100945-97-9.mol

Synonyms:(R,R)-(-)-[NBDRHDIPHOS] HEXAFLUOROPHOSPHATE, COMPLEX WITH ACETONE

Chemical Property of (R,R)-(-)-[NBDRHDIPHOS] HEXAFLUOROPHOSPHATE, COMPLEX WITH ACETONE

Chemical Property:

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (R,R)-(-)-[NBDRHDIPHOS] HEXAFLUOROPHOSPHATE, COMPLEX WITH ACETONE

There total 1 articles about (R,R)-(-)-[NBDRHDIPHOS] HEXAFLUOROPHOSPHATE, COMPLEX WITH ACETONE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

ammonium hexafluorophosphate + [(norbornadiene)rhodium(I)chloride]2 (12257-42-0) + (S,S)-1,2-bis(methylphenylphosphino)benzene (72091-01-1,72091-02-2,72150-36-8,72150-63-1,77410-05-0) → [R-(R*,R*)]-(bicyclo[2.2.1]hepta-2,5-diene)[1,2-phenylenebis(methylphenylphosphine)]rhodium(I) hexafluorophosphate*diacetone (100945-97-9)

Guidance literature:

With silver nitrate; acetone; In methanol; water; byproducts: AgCl; stirring of Rh compd. and AgNO3 in MeOH under Ar for 30 min, cooling to-78°C, addn. of ligand, after 1 h warming to room temp., filtn. of AgCl, treating with aq. NH4PF6; filtn., washing with water, drying, recrystn. from acetone and Et2O, elem. anal.;

DOI:10.1021/om00136a029

Reference yield: 49.0%

[R-(R*,R*)]-(bicyclo[2.2.1]hepta-2,5-diene)[1,2-phenylenebis(methylphenylphosphine)]rhodium(I) hexafluorophosphate*diacetone (100945-97-9) → Rh2(C6H4(PCH3C6H5)2)2(2+)*2PF6(1-)*CH2Cl2=Rh2(C6H4(PCH3C6H5)2)2(PF6)2*CH2Cl2 (100946-01-8)

Guidance literature:

With hydrogen; In dichloromethane; a soln. of Rh complex was stirred under 1 atm H2 for 15 h; filtn., recrystn. from hot CH2Cl2, elem. anal.;

DOI:10.1021/om00136a029

upstream raw materials:

[(norbornadiene)rhodium(I)chloride]2

(S,S)-1,2-bis(methylphenylphosphino)benzene

Downstream raw materials:

Rh₂(C₆H₄(PCH₃C₆H₅)2)2⁽²⁺⁾*2PF₆^(1-)*CH₂Cl₂=Rh₂(C₆H₄(PCH₃C₆H₅)2)2(PF₆)2*CH₂Cl₂