(1S,3R,5S)-2-Methylene-3-(hydroperoxy)-6,6-dimethylbicyclo[3.1.1]heptane

Base Information

Chemical Name:(1S,3R,5S)-2-Methylene-3-(hydroperoxy)-6,6-dimethylbicyclo[3.1.1]heptane
CAS No.:51131-99-8
Molecular Formula:C10H16O2
Molecular Weight:168.236
Hs Code.:
Mol file:51131-99-8.mol

Synonyms:(1S,3R,5S)-2-Methylene-3-(hydroperoxy)-6,6-dimethylbicyclo[3.1.1]heptane;[(1S,3R,5S)-6,6-Dimethyl-2-methylenebicyclo[3.1.1]heptane-3-yl] hydroperoxide;[(1β,5β)-2-Methylene-7,7-dimethylbicyclo[3.1.1]heptane-3α-yl] hydroperoxide;[[1S,3R,5S,(-)]-Pina-2(10)-ene]-3-yl hydroperoxide;Pinocarvyl hydroperoxide

Suppliers and Price of (1S,3R,5S)-2-Methylene-3-(hydroperoxy)-6,6-dimethylbicyclo[3.1.1]heptane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of (1S,3R,5S)-2-Methylene-3-(hydroperoxy)-6,6-dimethylbicyclo[3.1.1]heptane

Chemical Property:

Boiling Point:64 - 66.5 °C (0.001 mmHg)
PSA：29.46000
LogP:2.46680

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (1S,3R,5S)-2-Methylene-3-(hydroperoxy)-6,6-dimethylbicyclo[3.1.1]heptane

There total 12 articles about (1S,3R,5S)-2-Methylene-3-(hydroperoxy)-6,6-dimethylbicyclo[3.1.1]heptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 80-56-8,177698-18-9,25766-18-1
Pinene

: 22321-84-2,51131-99-8,51547-39-8,75992-91-5,129263-38-3
trans-pinocarveyl hydroperoxide

Guidance literature:: With oxygen; porphyrin-loaded polystyrene beads; Irradiation;
DOI:10.1039/b204017d

Reference yield: 66.0%

: 7785-70-8,25766-18-1
(+)-α-pinene

: 51131-99-8
(1S,3R,5S)-3-hydroperoxy-6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane

Guidance literature:: With oxygen; triphenylphosphine; In dichloromethane; at 20 ℃; for 10h; Reagent/catalyst; Irradiation;
DOI:10.1039/c7cc08957k

Reference yield: 18.0%

: 80-56-8,177698-18-9,25766-18-1
Pinene

: epidioxy-2,6 bornane

: 98513-99-6,98514-00-2
(1S,2R,5S)-2,6,6-Trimethyl-bicyclo[3.1.1]hept-3-en-2-yl-hydroperoxide

: 22321-84-2,51131-99-8,51547-39-8,75992-91-5,129263-38-3
cis hydroperoxy-3 pinene-2

: 22321-84-2,51131-99-8,51547-39-8,75992-91-5,129263-38-3
trans-pinocarveyl hydroperoxide

Guidance literature:: With oxygen; methylene blue; In water; acetonitrile; for 3.5h; Yield given. Further byproducts given. Yields of byproduct given; Irradiation;
DOI:10.1016/S0040-4039(00)93164-2