Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium (1:1)

Base Information

• Chemical Name: Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium (1:1)
• CAS No.: 898838-07-8
• Molecular Formula: C9H18Cl2MgN.Li
• Molecular Weight: 242.4
• Hs Code.: 29333990

Synonyms:Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium (1:1);2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution;2,2,6,6-TetraMethylpiperidinylMagnesiuM chloride lithiuM chloride coMplex solution 1.0 M in THF/toluene;2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex

Chemical Property of Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium (1:1)

Chemical Property:

• Flash Point: -15°C
• PSA: 0.00000
• Density: 0.96g/mLat 25℃
• LogP: -3.56030
• Storage Temp.: 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution 1.0 M in THF/toluene ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,C
• Statements: 63-11-14-19-34-37-40
• Safety Statements: 16-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex deprotonations using Knochel-Hauser-Base 2,2,6,6-Tetramethylpiperidinylmagnesium Chloride Lithium Chloride Complex is used in preparation of Pyridazinones as herbicides. Also, used in preparation of MCL-1 inhibitors useful for treatment of cancer. 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex is a non-nucleophilic Knochel-Hauser base mainly used for the magnesiation of functionalized arenes and heteroarenes to prepare the corresponding Grignard reagents. It can also be used as a base in the synthesis of Π-conjugated polymers via catalyst-transfer polycondensation.

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