3-(3-METHYL-3-BUTENYL)BENZOIC ACID

Base Information

• Chemical Name: 3-(3-METHYL-3-BUTENYL)BENZOIC ACID
• CAS No.: 732249-43-3
• Molecular Formula: C₁₂H₁₄O₂
• Molecular Weight: 190.242
• Hs Code.: 2916399090
• Mol file: 732249-43-3.mol

Synonyms:3-(3-METHYL-3-BUTENYL)BENZOIC ACID

Chemical Property of 3-(3-METHYL-3-BUTENYL)BENZOIC ACID

Chemical Property:

• Vapor Pressure: 0.000145mmHg at 25°C
• Boiling Point: 319°C at 760 mmHg
• Flash Point: 150.5°C
• PSA: 37.30000
• Density: 1.061g/cm³
• LogP: 2.89350

Purity/Quality:

97% ^*data from raw suppliers

3-(3-Methyl-3-butenyl)benzoicacid 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-(3-METHYL-3-BUTENYL)BENZOIC ACID

There total 2 articles about 3-(3-METHYL-3-BUTENYL)BENZOIC ACID which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C14H18O2 → 3-(3-methylbut-3-en-1-yl)benzoic acid (732249-43-3)

Guidance literature:

With tetraethylammonium hydroxide; In 1,4-dioxane; water; at 20 ℃; for 22h;

DOI:10.1002/anie.201307631

Reference yield:

ethyl 3-(((trifluoromethyl)sulfonyl)oxy)benzoate (1006714-38-0) + isopentenylmagnesium bromide (97344-88-2) → 3-(3-methylbut-3-en-1-yl)benzoic acid (732249-43-3)

Guidance literature:

Multi-step reaction with 2 steps

1: iron(III)-acetylacetonate / tetrahydrofuran; 1-methyl-pyrrolidin-2-one

2: tetraethylammonium hydroxide / water; 1,4-dioxane / 22 h / 20 °C

With iron(III)-acetylacetonate; tetraethylammonium hydroxide; In tetrahydrofuran; 1,4-dioxane; 1-methyl-pyrrolidin-2-one; water;

DOI:10.1002/anie.201307631

upstream raw materials:

ethyl 3-(((trifluoromethyl)sulfonyl)oxy)benzoate

isopentenylmagnesium bromide

Refernces