Dichloro(trifluoromethyl)arsine

Base Information

• Chemical Name: Dichloro(trifluoromethyl)arsine
• CAS No.: 421-32-9
• Molecular Formula: CAsCl2F3
• Molecular Weight: 214.834
• Mol file: 421-32-9.mol

Synonyms:Dichloro(trifluoromethyl)arsine

Chemical Property of Dichloro(trifluoromethyl)arsine

Chemical Property:

• Boiling Point: 80.15°C (estimate)
• PSA: 0.00000
• LogP: 2.47360

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Dichloro(trifluoromethyl)arsine

There total 11 articles about Dichloro(trifluoromethyl)arsine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

trifluoromethyl-arsonous acid diiodide (353-91-3) + silver(I) chloride → trifluoromethyldichloroarsine (421-32-9)

Guidance literature:

20°C, 12 d, in Carius tube; fractionated condensation;

Reference yield:

Trifluormethylarsonsaeure (374-03-8) → trifluoromethyldichloroarsine (421-32-9)

Guidance literature:

With sulfur dioxide; In hydrogenchloride; 0.5 h;

Reference yield:

Bis{bis(trifluormethyl)aminoxy}-trifluormethylarsan (32659-55-5) → trifluoromethyldichloroarsine (421-32-9)

Guidance literature:

With hydrogenchloride; at 100°C 1d, then trapped at -60°C;

DOI:10.1016/S0022-1139(00)81663-2

upstream raw materials:

trifluoromethyl-arsonous acid diiodide

bis(trifluoromethyl)chloroarsenic di

Trifluormethylarsonsaeure

tris(trifluoromethyl)arsine

Downstream raw materials:

tristrifluoromethylarsine

trifluoromethan

Refernces

• 1、 ANG, H. G.,SO, K. K.. "REACTIONS OF BIS(TRIFLUOROMETHYL)NITROXYL WITH (CF3)2AsX (WHERE X = F, Cl and Br)". . p. 433 - 450. Retrieved 2007/10/02.