(4-Methylphenyl)(4-nitrophenyl)diazene

Base Information

• Chemical Name: (4-Methylphenyl)(4-nitrophenyl)diazene
• CAS No.: 29418-58-4
• Molecular Formula: C13H11N3O2
• Molecular Weight: 241.249
• DSSTox Substance ID: DTXSID001038761
• Nikkaji Number: J959.886C
• Mol file: 29418-58-4.mol

Synonyms:29418-58-4;(4-METHYLPHENYL)(4-NITROPHENYL)DIAZENE;4-Methyl-4'-nitroazobenzene;SCHEMBL13869758;Azobenzene, 4-methyl-4'-nitro-;ILLZCQXUVXWGJA-CCEZHUSRSA-N;DTXSID001038761;STK672564;AKOS005592893;32968-59-5;(E)-(4-METHYLPHENYL)(4-NITROPHENYL)DIAZENE;(E)-1-(4-Methylphenyl)-2-(4-nitrophenyl)diazene;(E)-1-(4-Methylphenyl)-2-(4-nitrophenyl)diazene #;Diazene, 1-(4-methylphenyl)-2-(4-nitrophenyl)-, (1E)-

Chemical Property of (4-Methylphenyl)(4-nitrophenyl)diazene

Chemical Property:

• Vapor Pressure: 1.86E-06mmHg at 25°C
• Boiling Point: 406.8°Cat760mmHg
• Flash Point: 199.8°C
• Density: 1.21g/cm³
• XLogP3: 4.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 241.085126602
• Heavy Atom Count: 18
• Complexity: 298

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)N=NC2=CC=C(C=C2)[N+](=O)[O-]

Technology Process of (4-Methylphenyl)(4-nitrophenyl)diazene

There total 16 articles about (4-Methylphenyl)(4-nitrophenyl)diazene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

p-toluidine (106-49-0,12221-03-3) + 4-nitro-aniline (100-01-6,104810-17-5) → (E)-1-(4-nitrophenyl)-2-(p-tolyl)diazene (29418-58-4,79349-37-4,32968-59-5)

Guidance literature:

With p-tert-butylcalix[4]arene-tetra-O-acetate; silver nitrate; In water; at 60 ℃; for 1h; Darkness; Green chemistry;

DOI:10.1039/c5gc01859e

Reference yield: 65.0%

N'-p-tolyl-N-(4-nitro-phenyl)hydrazinecarboxylic acid tert-butyl ester → (E)-1-(4-nitrophenyl)-2-(p-tolyl)diazene (29418-58-4,79349-37-4,32968-59-5)

Guidance literature:

With pyridine; N-Bromosuccinimide; In dichloromethane; at 20 ℃; for 2h;

DOI:10.1021/ol027311u

Reference yield: 60.0%

p-toluidine (106-49-0,12221-03-3) + 4-nitro-aniline (100-01-6,104810-17-5) → (p-nitrophenylazo)toluene (29418-58-4)

Guidance literature:

With manganese oxide compound (MnOx); In N,N-dimethyl-formamide; at 80 ℃; for 12h; Autoclave;

upstream raw materials:

C₆H₄NCH₂CHCCH₂

4-nitrophenylhydrazone

1-methyl-4-nitrosobenzene

4-nitro-aniline