4,5,9,10-TetrabroMo-2,7-bis(2-octyldodecyl)benzo[lMn][3,8]phenanthroline-1,3,6,8-tetraone

Base Information

• Chemical Name: 4,5,9,10-TetrabroMo-2,7-bis(2-octyldodecyl)benzo[lMn][3,8]phenanthroline-1,3,6,8-tetraone
• CAS No.: 1219501-17-3
• Molecular Formula: C54H82Br4N2O4
• Molecular Weight: 1142.86
• Mol file: 1219501-17-3.mol

Synonyms:4,5,9,10-TetrabroMo-2,7-bis(2-octyldodecyl)benzo[lMn][3,8]phenanthroline-1,3,6,8-tetraone;4,5,9,10-tetrabromo-2,7-bis(2-octyldodecyl)benzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone;4,5,9,10-Tetrabromo-2,7-bis(2-octyldodecyl)benzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetrone

Chemical Property of 4,5,9,10-TetrabroMo-2,7-bis(2-octyldodecyl)benzo[lMn][3,8]phenanthroline-1,3,6,8-tetraone

Chemical Property:

• Boiling Point: 940.5±65.0 °C(Predicted)
• PKA: -4.46±0.20(Predicted)
• PSA: 78.14000
• Density: 1.291±0.06 g/cm3(Predicted)
• LogP: 17.91080

Purity/Quality:

97% ^*data from raw suppliers

4,5,9,10-Tetrabromo-2,7-bis(2-octyldodecyl)benzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4,5,9,10-TetrabroMo-2,7-bis(2-octyldodecyl)benzo[lMn][3,8]phenanthroline-1,3,6,8-tetraone

There total 3 articles about 4,5,9,10-TetrabroMo-2,7-bis(2-octyldodecyl)benzo[lMn][3,8]phenanthroline-1,3,6,8-tetraone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.7%

2-octyldodecylamine (62281-06-5) + 2,3,6,7-tetrabromonaphthalene-1,4,5,8-tetracarboxylic dianhydride (299962-88-2) → 4,5,9,10-tetrabromo-2,7-bis(2-octyldodecyl)benzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone (1219501-17-3)

Guidance literature:

With propionic acid; In o-xylene; at 140 ℃; for 2h;

DOI:10.1021/ja4118736

Reference yield: 33.0%

→ 4,5,9,10-tetrabromo-2,7-bis(2-octyldodecyl)benzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone (1219501-17-3)

Guidance literature:

Reference yield:

1,4,5,8-naphthalenetetracarboxylic dianhydride (81-30-1) → 4,5,9,10-tetrabromo-2,7-bis(2-octyldodecyl)benzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone (1219501-17-3)

Guidance literature:

Multi-step reaction with 2 steps

1.1: fuming sulphuric acid / 2 h / 55 °C

1.2: 50 h / 85 °C

2.1: propionic acid / o-xylene / 2 h / 140 °C

With fuming sulphuric acid; propionic acid; In o-xylene;

DOI:10.1021/ja4118736

upstream raw materials:

2-octyldodecylamine

2,3,6,7-tetrabromonaphthalene-1,4,5,8-tetracarboxylic dianhydride

1,4,5,8-naphthalenetetracarboxylic dianhydride

Downstream raw materials:

C₆₁H₈₇Br₂N₃O₄S