5-Hydroxydihydrosterigmatocystin

Base Information

• Chemical Name: 5-Hydroxydihydrosterigmatocystin
• CAS No.: 6795-16-0
• Molecular Formula: C18H14O6
• Molecular Weight: 326.32
• DSSTox Substance ID: DTXSID50987337
• Wikidata: Q104196588
• Mol file: 6795-16-0.mol

Synonyms:5-Hydroxydihydrosterigmatocystin;CCRIS 3210;SCHEMBL19185991;DTXSID50987337;7H-Furo[3',2':4,5]furo[2,3-c]xanthen-7-one, 1,2,3a,12c-tetrahydro-8-hydroxy-6-methoxy-;LS-70777;1,2-Dihydro-6-methoxy-7-hydroxyfuroxanthone;8-Hydroxy-6-methoxy-1,2,3a,12c-tetrahydro-7H-furo[3',2':4,5]furo[2,3-c]xanthen-7-one

Chemical Property of 5-Hydroxydihydrosterigmatocystin

Chemical Property:

• Melting Point: >300 °C
• Boiling Point: 562°Cat760mmHg
• PKA: 6.93±0.20(Predicted)
• Flash Point: 211.7°C
• PSA: 78.13000
• Density: 1.473g/cm³
• LogP: 2.88280
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 1
• Exact Mass: 326.07903816
• Heavy Atom Count: 24
• Complexity: 524

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=C2C(=C3C4CCOC4OC3=C1)OC5=CC=CC(=C5C2=O)O

Technology Process of 5-Hydroxydihydrosterigmatocystin

There total 3 articles about 5-Hydroxydihydrosterigmatocystin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sterigmatocystin (10048-13-2) → dihydrosterigmatocystin (6795-16-0)

Guidance literature:

With hydrogen; palladium on activated charcoal; In ethyl acetate; for 5h; under 1551.44 Torr;

DOI:10.1021/ja0455188

Reference yield:

→ dihydrosterigmatocystin (6795-16-0)

Guidance literature:

aus Sterigmatocystin, H2/Pd;

DOI:10.1021/jo00442a034

Reference yield:

→ dihydrosterigmatocystin (6795-16-0)

Guidance literature:

Sterigmatocystin (12), H2/Pd-C;

upstream raw materials:

sterigmatocystin

Downstream raw materials:

6,8-dimethoxy-1,2,3a,12c-tetrahydrofuro[2,3-c]furoxanth-7-one

Refernces

• 1、 Chen,Kingston,Vercellotti. "Reduction of sterigmatocystin and versicolorin A hemiacetals with sodium borohydride". . p. 3599 - 3605. Retrieved 2007/10/10.