Phenyl 3-O-(phenylmethyl)-1-thio-alpha-L-idopyranosiduronic acid methyl ester 2-benzoate

Base Information

Chemical Name:Phenyl 3-O-(phenylmethyl)-1-thio-alpha-L-idopyranosiduronic acid methyl ester 2-benzoate
CAS No.:616876-73-4
Molecular Formula:C27H26O7S
Molecular Weight:494.565
Hs Code.:

Synonyms:Phenyl 3-O-(phenylmethyl)-1-thio-alpha-L-idopyranosiduronic acid methyl ester 2-benzoate

Suppliers and Price of Phenyl 3-O-(phenylmethyl)-1-thio-alpha-L-idopyranosiduronic acid methyl ester 2-benzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemicals and raw materials
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Total 1 raw suppliers

Chemical Property of Phenyl 3-O-(phenylmethyl)-1-thio-alpha-L-idopyranosiduronic acid methyl ester 2-benzoate

Chemical Property:

Purity/Quality:: 95% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Phenyl 3-O-(phenylmethyl)-1-thio-alpha-L-idopyranosiduronic acid methyl ester 2-benzoate

There total 16 articles about Phenyl 3-O-(phenylmethyl)-1-thio-alpha-L-idopyranosiduronic acid methyl ester 2-benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 175978-45-7
(2R,3S,4S,5R,6S)-5-Benzoyloxy-4-benzyloxy-3-(4-oxo-pentanoyloxy)-6-phenylsulfanyl-tetrahydro-pyran-2-carboxylic acid methyl ester

: 616876-73-4
methyl (phenyl 2-O-benzoyl-3-O-benzyl-1-thio-α-L-idopyranoside)uronate

Guidance literature:: With hydrazinium monoacetate; In methanol; dichloromethane; at 20 ℃; for 1h;
DOI:10.1016/j.carres.2006.02.020

Reference yield: 83.0%

: 850637-33-1
phenyl 2-O-benzoyl-3-O-benzyl-1-thio-α-L-idopyranosyluronic acid

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 616876-73-4
methyl (phenyl 2-O-benzoyl-3-O-benzyl-1-thio-α-L-idopyranoside)uronate

Guidance literature:: In diethyl ether; N,N-dimethyl-formamide; for 0.0833333h;
DOI:10.1021/ja045613g

Reference yield:

: (4aS,7R,8R,8aR)-8-Benzyloxy-2,2-dimethyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

: 616876-73-4
methyl (phenyl 2-O-benzoyl-3-O-benzyl-1-thio-α-L-idopyranoside)uronate

Guidance literature:: Multi-step reaction with 4 steps

1: pyridine / 2 h

2: aq. AcOH / 2 h / 60 °C

3: 81 percent / TEMPO; [bis(acetoxy)iodo]benzene / CH₂Cl₂; H₂O / 0.5 h

4: 83 percent / dimethylformamide; diethyl ether / 0.08 h

With pyridine; 2,2,6,6-tetramethyl-piperidine-N-oxyl; [bis(acetoxy)iodo]benzene; acetic acid; In diethyl ether; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1021/ja045613g