(o-Nitrophenyl)-p-benzoquinone

Base Information

• Chemical Name: (o-Nitrophenyl)-p-benzoquinone
• CAS No.: 105946-79-0
• Molecular Formula: C₁₂H₇NO₄
• Molecular Weight: 229.192
• Mol file: 105946-79-0.mol

Synonyms:(o-Nitrophenyl)-p-benzoquinone;2-(2-Nitrophenyl)-2,5-cyclohexadiene-1,4-dione

Chemical Property of (o-Nitrophenyl)-p-benzoquinone

Chemical Property:

• PSA: 79.96000
• LogP: 2.20940
• Solubility.: Chloroform, Dichloromethane, Ethyl Acetate

Purity/Quality:

98%min ^*data from raw suppliers

(o-Nitrophenyl)-p-benzoquinone ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: (o-Nitrophenyl)-p-benzoquinone is a reactant used in the preparation of monoaryl-p-benzoquinones.

Technology Process of (o-Nitrophenyl)-p-benzoquinone

There total 2 articles about (o-Nitrophenyl)-p-benzoquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

2-nitro-aniline (88-74-4) + p-benzoquinone (106-51-4) → 2'-nitro-[1,1'-biphenyl]-2,5-dione (105946-79-0)

Guidance literature:

2-nitro-aniline; With methanesulfonic acid; 2,2-dimethylpropyl nitrite; In water; at 25 ℃; for 0.166667h; Green chemistry;

p-benzoquinone; In water; at 20 ℃; for 12h; Irradiation; Green chemistry;

DOI:10.1039/c8gc00012c

Reference yield:

→ 2'-nitro-[1,1'-biphenyl]-2,5-dione (105946-79-0)

Guidance literature:

/BRN= 3322996/;

DOI:10.1139/v58-120

Reference yield:

2'-nitro-[1,1'-biphenyl]-2,5-dione (105946-79-0) → 3-Hydroxycarbazol (7384-07-8)

Guidance literature:

With ethanol; nickel; Hydrogenation;

upstream raw materials:

2-nitro-aniline

p-benzoquinone

Downstream raw materials:

3-Hydroxycarbazol

2'-Amino-biphenyl-2,5-diol

Refernces