N,N'-Bis(2-ethylhexyloxy)-1,7-dibroMo-3,4,9,10-perylene diiMide

Base Information

• Chemical Name: N,N'-Bis(2-ethylhexyloxy)-1,7-dibroMo-3,4,9,10-perylene diiMide
• CAS No.: 851786-15-7
• Molecular Formula: C40H40Br2N2O4
• Molecular Weight: 772.577
• Mol file: 851786-15-7.mol

Synonyms:N,N'-Bis(2-ethylhexyloxy)-1,7-dibroMo-3,4,9,10-perylene diiMide;5,12-DibroMo-2,9-bis(2-ethylhexyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone;N,N'-bis(2-ethylhexyl)-1,7-dibromo-3,4,9,10-perylene tetracarboxylic diimide;PDT32

Chemical Property of N,N'-Bis(2-ethylhexyloxy)-1,7-dibroMo-3,4,9,10-perylene diiMide

Chemical Property:

• Boiling Point: 833.5±65.0 °C(Predicted)
• PKA: -2.83±0.20(Predicted)
• PSA: 78.14000
• Density: 1.461±0.06 g/cm3(Predicted)
• LogP: 9.92080
• Storage Temp.: Inert atmosphere,Room Temperature

Purity/Quality:

97% ^*data from raw suppliers

5,12-Dibromo-2,9-bis(2-ethylhexyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N,N'-Bis(2-ethylhexyloxy)-1,7-dibroMo-3,4,9,10-perylene diiMide

There total 11 articles about N,N'-Bis(2-ethylhexyloxy)-1,7-dibroMo-3,4,9,10-perylene diiMide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

2-Ethylhexylamine (104-75-6) + 1,7-dibromoperylene-3,4,9,10-tetracarboxylic dianhydride (118129-60-5) → N,N'-di(2-ethylhexyl)-1,7-dibromoperylene-3,4,9,10-bisdicarboximide (851786-15-7)

Guidance literature:

In propionic acid; at 140 ℃; for 12h; Inert atmosphere;

DOI:10.1016/j.polymer.2010.04.035

Reference yield: 78.0%

2,9-bis(2-ethylhexyl)anthra[2,1,9-def:6,5,10-d',e',f']diisoquinoline-1,3,8,10(2H,9H)-tetraone (82531-03-1) → N,N'-di(2-ethylhexyl)-1,7-dibromoperylene-3,4,9,10-bisdicarboximide (851786-15-7)

Guidance literature:

With bromine; In dichloromethane; at 60 ℃; for 72h;

DOI:10.1002/pola.27108

Reference yield: 22.0%

2,9-bis(2-ethylhexyl)anthra[2,1,9-def:6,5,10-d',e',f']diisoquinoline-1,3,8,10(2H,9H)-tetraone (82531-03-1) → N,N'-di(2-ethylhexyl)-1,7-dibromoperylene-3,4,9,10-bisdicarboximide (851786-15-7) + 5-bromo-2,9-bis(2-ethylhexyl)anthra[2,1,9-def:6,5,10-d',e',f']diisoquinoline-1,3,8,10(2H,9H)-tetraone (1015473-19-4)

Guidance literature:

With bromine; In chloroform; at 20 ℃; for 48h;

DOI:10.1039/c3dt33036b

upstream raw materials:

2-Ethylhexylamine

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride

1,7-dibromoperylene-3,4,9,10-tetracarboxylic dianhydride

2,9-bis(2-ethylhexyl)anthra[2,1,9-def:6,5,10-d',e',f']diisoquinoline-1,3,8,10(2H,9H)-tetraone

Downstream raw materials:

N,N'-di(2-ethylhexyl)-1,7-dithien-2-yl-3,4,9,10-perylenediimide

1,7-bis[4-(diphenylamino)phenyl] N,N'-2-ethylhexyl perylene bisimide

C₅₆H₄₈F₆N₂O₈

C₆₀H₆₆N₂O₆