6,7,8,13,14,15-Hexahydro-7,14-methanobenzo[6,7]cyclodeca[1,2-b]naphthalen-17-one

Base Information

Chemical Name:6,7,8,13,14,15-Hexahydro-7,14-methanobenzo[6,7]cyclodeca[1,2-b]naphthalen-17-one
CAS No.:108395-69-3
Molecular Formula:C₂₃H₂₀O
Molecular Weight:312.411
Hs Code.:
DSSTox Substance ID:DTXSID601347964
Nikkaji Number:J414.135K
Mol file:108395-69-3.mol

Synonyms:108395-69-3;6,7,8,13,14,15-Hexahydro-7,14-methanobenzo[6,7]cyclodeca[1,2-b]naphthalen-17-one;pentacyclo[12.8.1.03,12.05,10.016,21]tricosa-3,5,7,9,11,16,18,20-octaen-23-one;DTXSID601347964;BENZO(C)NAPHTHO(2,3-H)BICYCLO(4.4.1)UNDECA-3,8-DIEN-11-ONE

Suppliers and Price of 6,7,8,13,14,15-Hexahydro-7,14-methanobenzo[6,7]cyclodeca[1,2-b]naphthalen-17-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 6,7,8,13,14,15-Hexahydro-7,14-methanobenzo[6,7]cyclodeca[1,2-b]naphthalen-17-one

Chemical Property:

Melting Point:190 - 192 °C (benzene)
PSA：17.07000
LogP:4.53870
XLogP3:5.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:312.151415257
Heavy Atom Count:24
Complexity:440

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1C2CC3=CC4=CC=CC=C4C=C3CC(C2=O)CC5=CC=CC=C51

Technology Process of 6,7,8,13,14,15-Hexahydro-7,14-methanobenzo[6,7]cyclodeca[1,2-b]naphthalen-17-one

There total 6 articles about 6,7,8,13,14,15-Hexahydro-7,14-methanobenzo[6,7]cyclodeca[1,2-b]naphthalen-17-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 38998-33-3
2,3-di(bromomethyl)naphthalene

: 108395-69-3
benzonaphtho<2,3-h>bicyclo<4.4.1>undeca-3,8-dien-11-one

Guidance literature:: Multi-step reaction with 4 steps

1: 49 percent / Bu₄NBr, 8percent aq. NaHCO₃ / CH₂Cl₂ / 40 h

2: 61 percent / Bu₄NCl, 23 percent aq. NaOH

3: KOH / ethanol; H₂O / 2.5 h

4: 0.31 g / 280 °C

With potassium hydroxide; sodium hydroxide; tetrabutylammomium bromide; tetrabutyl-ammonium chloride; sodium hydrogencarbonate; In ethanol; dichloromethane; water;
DOI:10.1021/jo00389a004

Reference yield:

: 108395-67-1
dimethyl benzonaphtho<2,3-h>-11-oxobicyclo<4.4.1>undeca-3,8-diene-1,6-dicarboxylate

: 108395-69-3
benzonaphtho<2,3-h>bicyclo<4.4.1>undeca-3,8-dien-11-one

Guidance literature:: Multi-step reaction with 2 steps

1: KOH / ethanol; H₂O / 2.5 h

2: 0.31 g / 280 °C

With potassium hydroxide; In ethanol; water;
DOI:10.1021/jo00389a004

Reference yield:

: 24790-66-7
dimethyl 1,2,4,5-tetrahydro-3-oxobenzocycloheptene-2,4-dicarboxylate

: 108395-69-3
benzonaphtho<2,3-h>bicyclo<4.4.1>undeca-3,8-dien-11-one

Guidance literature:: Multi-step reaction with 3 steps

1: 60 percent / Bu₄NCl, 23 percent aq. NaOH / CH₂Cl₂ / 25 h / Ambient temperature

2: KOH / ethanol; H₂O / 2.5 h

3: 0.31 g / 280 °C

With potassium hydroxide; sodium hydroxide; tetrabutyl-ammonium chloride; In ethanol; dichloromethane; water;
DOI:10.1021/jo00389a004