4,4'-Dibutoxy-2,2'-bis(trimethylstannyl)-5,5'-bithiazole

Base Information

• Chemical Name: 4,4'-Dibutoxy-2,2'-bis(trimethylstannyl)-5,5'-bithiazole
• CAS No.: 1224430-28-7
• Molecular Formula: C62H102Br2N2O2S2
• Molecular Weight: 1131.42
• Mol file: 1224430-28-7.mol

Synonyms:4,4'-Dibutoxy-2,2'-bis(trimethylstannyl)-5,5'-bithiazole

Chemical Property of 4,4'-Dibutoxy-2,2'-bis(trimethylstannyl)-5,5'-bithiazole

Chemical Property:

• Boiling Point: 983.2±65.0 °C(Predicted)
• PKA: -5.38±0.60(Predicted)
• PSA: 100.48000
• Density: 1.15±0.1 g/cm3(Predicted)
• LogP: 22.45060

Purity/Quality:

99.3% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4,4'-Dibutoxy-2,2'-bis(trimethylstannyl)-5,5'-bithiazole

There total 6 articles about 4,4'-Dibutoxy-2,2'-bis(trimethylstannyl)-5,5'-bithiazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

2,5-bis(2-decyltetradecyl)-3,6-di(thiophen-2-yl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione (1312588-15-0) → 3,6-bis(5-bromothiophen-2-yl)-2,5-bis(2-decyltetradecyl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione (1224430-28-7)

Guidance literature:

With N-Bromosuccinimide; In chloroform; at 20 ℃; Inert atmosphere; Schlenk technique;

DOI:10.1002/pola.27500

Reference yield:

2,5-bis(2-octyldodecyl)-3,6-di(thiophen-2-yl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione (1267540-02-2) → 3,6-bis(5-bromothiophen-2-yl)-2,5-bis(2-decyltetradecyl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione (1224430-28-7)

Guidance literature:

With N-Bromosuccinimide; In N,N-dimethyl-formamide; at 50 ℃;

DOI:10.1039/c3tc32219j

Reference yield:

3,6-dithiophen-2-yl-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione + 11-bromomethyl-tricosane (732276-63-0) → 3,6-bis(5-bromothiophen-2-yl)-2,5-bis(2-decyltetradecyl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione (1224430-28-7)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium carbonate / N,N-dimethyl-formamide / 155 °C / Inert atmosphere; Schlenk technique

2: N-Bromosuccinimide / chloroform / Inert atmosphere; Schlenk technique

With N-Bromosuccinimide; potassium carbonate; In chloroform; N,N-dimethyl-formamide;

DOI:10.1021/cm5014703

upstream raw materials:

2,5-bis(2-decyltetradecyl)-3,6-di(thiophen-2-yl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione

2-octyldodecan-1-ol

2,5-bis(2-octyldodecyl)-3,6-di(thiophen-2-yl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione

11-bromomethyl-tricosane