Carbonic acid methyl 3-nitrophenyl ester

Base Information

• Chemical Name: Carbonic acid methyl 3-nitrophenyl ester
• CAS No.: 17175-17-6
• Molecular Formula: C8H7NO5
• Molecular Weight: 197.147
• Mol file: 17175-17-6.mol

Synonyms:Carbonic acid methyl 3-nitrophenyl ester;Carbonic acid methyl m-nitrophenyl ester;Carbonic acid methyl(m-nitrophenyl) ester

Chemical Property of Carbonic acid methyl 3-nitrophenyl ester

Chemical Property:

• PSA: 81.35000
• LogP: 2.26320

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Carbonic acid methyl 3-nitrophenyl ester

There total 2 articles about Carbonic acid methyl 3-nitrophenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

meta-nitrophenol (554-84-7) + carbonic acid dimethyl ester (616-38-6) → 3-nitroanisole (555-03-3) + methyl 3-nitrophenyl carbonate (17175-17-6)

Guidance literature:

With aluminum (III) chloride; at 90 ℃; for 19h; Molecular sieve; Green chemistry;

DOI:10.1039/c6gc01826b

Reference yield:

meta-nitrophenol (554-84-7) + methyl chloroformate (79-22-1) → methyl 3-nitrophenyl carbonate (17175-17-6)

Guidance literature:

With sodium hydride; Multistep reaction; 1) THF 2) 3h, room temperature;

DOI:10.1016/S0040-4020(01)89753-2

Reference yield:

methyl 3-nitrophenyl carbonate (17175-17-6) → 3-nitroanisole (555-03-3)

Guidance literature:

N,N,N',N'-tetrabutyl-N''-methylguanidine; at 110 ℃; for 1h;

DOI:10.1016/S0040-4020(01)89753-2

upstream raw materials:

meta-nitrophenol

methyl chloroformate

carbonic acid dimethyl ester

Downstream raw materials:

3-nitroanisole

Refernces

• 1、 Neverov, Alexei A.,Chen, Leanne D.,George, Sean,Simon, David,Maxwell, Christopher I.,Brown, R. Stan. "A mechanistic study of the [La2(OCH3) 2]4+-and [(1,5,9-triazacyclodo-decane):Zn:(OCH 3)]+-catalyzed methanolysis of carbonates: Possible application for the recycling of bisphenol A polycar". . p. 1139 - 1146. Retrieved 2013/11/06.