2,5-ANHYDRO-D-MANNITOL-1-PHOSPHATE, BARIUM SALT HYDRATE

Base Information

• Chemical Name: 2,5-ANHYDRO-D-MANNITOL-1-PHOSPHATE, BARIUM SALT HYDRATE
• CAS No.: 52011-52-6
• Molecular Formula: C₆H₁₃O₈P
• Molecular Weight: 244.138
• Mol file: 52011-52-6.mol

Synonyms:2,5-Anhydro-D-mannitol1-phosphate; 2,5-Anhydro-D-mannitol-6-phosphate

Chemical Property of 2,5-ANHYDRO-D-MANNITOL-1-PHOSPHATE, BARIUM SALT HYDRATE

Chemical Property:

• Vapor Pressure: 1.89E-15mmHg at 25°C
• Boiling Point: 571.7°Cat760mmHg
• Flash Point: 299.5°C
• PSA: 161.38000
• Density: 1.757g/cm³
• LogP: -1.61070
• Storage Temp.: -20°C Freezer
• Solubility.: Water (Slightly, Heated, Sonicated)

Purity/Quality:

98%Min ^*data from raw suppliers

2,5-Anhydro-D-mannitol-1-phosphate barium salt hydrate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Uses: Inhibits gluconeogenesis in isolated hepatcytes as well as preventing hormonal stimulation of gluconeogenesis and the corresponding decrease in lactate production from dihydroxyacetone 2,5-Anhydro-D-mannitol-1-phosphate, Barium Salt Hydrate inhibits gluconeogenesis in isolated hepatcytes as well as preventing hormonal stimulation of gluconeogenesis and the corresponding decrease in lactate production from dihydroxyacetone.

Technology Process of 2,5-ANHYDRO-D-MANNITOL-1-PHOSPHATE, BARIUM SALT HYDRATE

There total 9 articles about 2,5-ANHYDRO-D-MANNITOL-1-PHOSPHATE, BARIUM SALT HYDRATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,5-anhydro-D-mannitol 6-diphenylphosphate → Phosphoric acid mono-((2R,3S,4S,5R)-3,4-dihydroxy-5-hydroxymethyl-tetrahydro-furan-2-ylmethyl) ester (52011-52-6)

Guidance literature:

With hydrogen; platinum(IV) oxide; In methanol; for 18h;

DOI:10.1021/jo0003908

Reference yield:

2,5-anhydro-3,4,6-tris-O-(phenylmethyl)-D-mannose (94273-27-5) → Phosphoric acid mono-((2R,3S,4S,5R)-3,4-dihydroxy-5-hydroxymethyl-tetrahydro-furan-2-ylmethyl) ester (52011-52-6)

Guidance literature:

Multi-step reaction with 4 steps

1: 80 percent / NaBH₄ / ethanol / 2 h

2: 51 percent / DMAP; pyridine / 18 h / 0 - 20 °C

3: H₂ / Pd/C / methanol / 18 h

4: H₂ / PtO₂ / methanol / 18 h

With pyridine; dmap; sodium tetrahydroborate; hydrogen; platinum(IV) oxide; palladium on activated charcoal; In methanol; ethanol; 1: Reduction / 2: Condensation / 3: Hydrogenolysis / 4: Hydrogenolysis;

DOI:10.1021/jo0003908

Reference yield:

2,5-anhydro-3,4,6-tri-O-benzyl-D-mannitol (102208-55-9) → Phosphoric acid mono-((2R,3S,4S,5R)-3,4-dihydroxy-5-hydroxymethyl-tetrahydro-furan-2-ylmethyl) ester (52011-52-6)

Guidance literature:

Multi-step reaction with 3 steps

1: 51 percent / DMAP; pyridine / 18 h / 0 - 20 °C

2: H₂ / Pd/C / methanol / 18 h

3: H₂ / PtO₂ / methanol / 18 h

With pyridine; dmap; hydrogen; platinum(IV) oxide; palladium on activated charcoal; In methanol; 1: Condensation / 2: Hydrogenolysis / 3: Hydrogenolysis;

DOI:10.1021/jo0003908

upstream raw materials:

2,5-anhydro-3,4,6-tris-O-(phenylmethyl)-D-mannose

2,5-anhydro-3,4,6-tri-O-benzyl-D-mannitol

3,6-anhydro-4,5,7-tri-O-benzyl-1,2-dideoxy-D-gluco-hept-1-enitol

3,6-anhydro-4,5,7-tri-O-benzyl-1,2-dideoxy-D-manno-hept-1-enitol

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 52011-52-6 2,5-ANHYDRO-D-MANNITOL-1-PHOSPHATE, BARIUM SALT HYDRATE

Send

Send

Metric Ton KG G Pound L ML

Send

Send