2-(2-oxoethyl)-1,3-Dioxolane-2-acetic acid ethyl ester

Base Information

Chemical Name:2-(2-oxoethyl)-1,3-Dioxolane-2-acetic acid ethyl ester
CAS No.:32296-85-8
Molecular Formula:C₉H₁₄O₅
Molecular Weight:202.207
Hs Code.:
Mol file:32296-85-8.mol

Synonyms:2-(2-oxoethyl)-1,3-Dioxolane-2-acetic acid ethyl ester

Suppliers and Price of 2-(2-oxoethyl)-1,3-Dioxolane-2-acetic acid ethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 3 raw suppliers

Chemical Property of 2-(2-oxoethyl)-1,3-Dioxolane-2-acetic acid ethyl ester

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

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Hazard Codes:

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Technology Process of 2-(2-oxoethyl)-1,3-Dioxolane-2-acetic acid ethyl ester

There total 1 articles about 2-(2-oxoethyl)-1,3-Dioxolane-2-acetic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 71022-90-7
diethyl 2,2'-(1,3-dioxolane-2,2-diyl)diacetate

: 32296-85-8
ethyl 3,3-(ethylenedioxy)-4-formylbutyrate

: 127747-11-9
1,3-DIOXOLANE-2,2-DIACETALDEHYDE

Guidance literature:: With diisobutylaluminium hydride; In toluene; at -78 ℃; for 1.16667h; Title compound not separated from byproducts;
DOI:10.1016/S0040-4039(01)00409-9

Reference yield: 36.0%

: 32296-85-8
ethyl 3,3-(ethylenedioxy)-4-formylbutyrate

: C₁₈H₁₉NO₃

: C₂₇H₃₃NO₈

: C₂₇H₃₃NO₈

Guidance literature:: With tetrabutylammomium bromide; potassium carbonate; In dichloromethane; at 20 ℃; for 5h; Inert atmosphere;
DOI:10.1002/chem.201604620

Reference yield:

: 32296-85-8
ethyl 3,3-(ethylenedioxy)-4-formylbutyrate

: 75321-07-2
(3S,4R)-3-[(R)-1-hydroxyethyl]-4-[3-(4-nitrobenzyl)-oxycarbonyl-2-oxopropyl]azetidin-2-one

Guidance literature:: Multi-step reaction with 7 steps

1: benzene / 1 h / 50 °C

2: 22.7 percent / benzene / 16 h / Heating

3: H₂, AcOH / 10percent Pd/C / 38 h / 3420 Torr / Ambient temperature

4: N,N'-dicyclohexylcarbodiimide / acetonitrile / 3 h / 60 °C

5: 57.8 percent / Et₃N / dimethylformamide / 18 h / Ambient temperature

6: 1.) aq. NaOH / 1.) THF, RT, 2 h, 2.) DMF, RT, 2 h

7: 89.9 percent / conc. hydrochloric acid / methanol / 2 h / 5 °C

With hydrogenchloride; sodium hydroxide; hydrogen; acetic acid; triethylamine; dicyclohexyl-carbodiimide; palladium on activated charcoal; In methanol; N,N-dimethyl-formamide; acetonitrile; benzene;
DOI:10.1021/jo00213a025