(1,5-Cyclooctadiene)[(3R,4R)-3,4-bis(diphenylphosphino)-1-methylpyrrolidine]rhodium Tetrafluoroborate

Base Information

• Chemical Name: (1,5-Cyclooctadiene)[(3R,4R)-3,4-bis(diphenylphosphino)-1-methylpyrrolidine]rhodium Tetrafluoroborate
• CAS No.: 100366-06-1
• Molecular Formula: BF₄*C₃₇H₄₁NP₂Rh
• Molecular Weight: 751.397
• Mol file: 100366-06-1.mol

Synonyms:(1,5-Cyclooctadiene)[(3R,4R)-3,4-bis(diphenylphosphino)-1-methylpyrrolidine]rhodium Tetrafluoroborate

Chemical Property of (1,5-Cyclooctadiene)[(3R,4R)-3,4-bis(diphenylphosphino)-1-methylpyrrolidine]rhodium Tetrafluoroborate

Chemical Property:

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (1,5-Cyclooctadiene)[(3R,4R)-3,4-bis(diphenylphosphino)-1-methylpyrrolidine]rhodium Tetrafluoroborate

There total 1 articles about (1,5-Cyclooctadiene)[(3R,4R)-3,4-bis(diphenylphosphino)-1-methylpyrrolidine]rhodium Tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

rhodium(I)-bis(1,5-cyclooctadiene) tetrafluoroborate + {(3R,4R)-3,4-bis(diphenylphosphino)-1-methylpyrrolidine (100350-84-3) → {(3R,4R)-(1-methyl-3,4-pyrrolidindiyl)bis(diphenylphosphane)}(1,5-cyclooctadiene)rhodium tetrafluoroborate (100366-06-1)

Guidance literature:

In dichloromethane; (Ar); Rh complex added to a soln. of the pyrrolidine in CH2Cl2; soln. stirred overnight; addn. of ether, ppt. centrifuged, washed with ether, dried in high vac., elem. anal.;

Reference yield: 96.0%

{(3R,4R)-(1-methyl-3,4-pyrrolidindiyl)bis(diphenylphosphane)}(1,5-cyclooctadiene)rhodium tetrafluoroborate (100366-06-1) + trimethoxonium tetrafluoroborate (420-37-1) → {(3R,4R)-3,4-bis(diphenylphosphino)-1,1-dimethylpyrrolidinium-P,P'}(1,5-cyclooctadiene)rhodium bis(tetrafluoroborate) (100366-08-3)

Guidance literature:

In dichloromethane; (Ar); the Rh complex is added to the oxonium salt suspended in CH2Cl2, mixt. stirred overnight; addn. of Et2O, ppt. centrifuged, washed with Et2O, dried in high vac., elem. anal.;

upstream raw materials:

{(3R,4R)-3,4-bis(diphenylphosphino)-1-methylpyrrolidine

Downstream raw materials:

{(3R,4R)-3,4-bis(diphenylphosphino)-1,1-dimethylpyrrolidinium-P,P'}(1,5-cyclooctadiene)rhodium bis(tetrafluoroborate)

Refernces