2-[(acetyloxy)methyl]-6-[(4,4-dimethyl-3,5,10,11-tetraoxatricyclo[6.2.1.0~2,6~]undec-7-yl)oxy]tetrahydro-2H-pyran-3,4,5-triyl triacetate (non-preferred name)

Base Information

• Chemical Name: 2-[(acetyloxy)methyl]-6-[(4,4-dimethyl-3,5,10,11-tetraoxatricyclo[6.2.1.0~2,6~]undec-7-yl)oxy]tetrahydro-2H-pyran-3,4,5-triyl triacetate (non-preferred name)
• CAS No.: 5346-69-0
• Molecular Formula: C21H35Cl4N
• Molecular Weight: 443.3213
• Mol file: 5346-69-0.mol

Synonyms:Dodecyl dimethyl trichlorobenzyl ammonium chloride

Chemical Property of 2-[(acetyloxy)methyl]-6-[(4,4-dimethyl-3,5,10,11-tetraoxatricyclo[6.2.1.0~2,6~]undec-7-yl)oxy]tetrahydro-2H-pyran-3,4,5-triyl triacetate (non-preferred name)

Chemical Property:

• Vapor Pressure: 5.43E-13mmHg at 25°C
• Boiling Point: 569.7°C at 760 mmHg
• Flash Point: 242.2°C
• Density: 1.38g/cm³

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-[(acetyloxy)methyl]-6-[(4,4-dimethyl-3,5,10,11-tetraoxatricyclo[6.2.1.0~2,6~]undec-7-yl)oxy]tetrahydro-2H-pyran-3,4,5-triyl triacetate (non-preferred name)

There total 1 articles about 2-[(acetyloxy)methyl]-6-[(4,4-dimethyl-3,5,10,11-tetraoxatricyclo[6.2.1.0~2,6~]undec-7-yl)oxy]tetrahydro-2H-pyran-3,4,5-triyl triacetate (non-preferred name) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide (572-09-8) → O2,O3-isopropylidene-O4-(tetra-O-acetyl-β-D-glucopyranosyl)-1,6-anhydro-β-D-mannopyranose (5346-69-0)

Guidance literature:

With chloroform; iodine; silver(l) oxide; Reagens 4: Calciumsulfat;

DOI:10.1021/ja01851a065

Reference yield:

O2,O3-isopropylidene-O4-(tetra-O-acetyl-β-D-glucopyranosyl)-1,6-anhydro-β-D-mannopyranose (5346-69-0) → O2,O3-Diacetyl-O4-(tetra-O-acetyl-β-D-glucopyranosyl)-1,6-anhydro-β-D-mannopyranose (2672-62-0,25878-57-3,28868-67-9,38631-27-5,56907-27-8,61117-14-4,61278-03-3,78215-48-2,139013-90-4)

Guidance literature:

Multi-step reaction with 2 steps

1: aqueous acetic acid

2: pyridine

With pyridine; acetic acid;

DOI:10.1021/ja01851a065

Reference yield:

O2,O3-isopropylidene-O4-(tetra-O-acetyl-β-D-glucopyranosyl)-1,6-anhydro-β-D-mannopyranose (5346-69-0) → O4-(Tetra-O-acetyl-β-D-glucopyranosyl)-1,6-anhydro-β-D-mannopyranose (7225-54-9,67650-35-5)

Guidance literature:

With acetic acid;

DOI:10.1021/ja01851a065

upstream raw materials:

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

Downstream raw materials:

O⁴-(Tetra-O-acetyl-β-D-glucopyranosyl)-1,6-anhydro-β-D-mannopyranose

O²,O³-Diacetyl-O⁴-(tetra-O-acetyl-β-D-glucopyranosyl)-1,6-anhydro-β-D-mannopyranose