5-Hydroxy-clethodiM Sulfoxide

Base Information

Chemical Name:5-Hydroxy-clethodiM Sulfoxide
CAS No.:111031-08-4
Molecular Formula:C₁₇H₂₆ClNO₅S
Molecular Weight:391.916
Hs Code.:
Mol file:111031-08-4.mol

Synonyms:5-Hydroxy-clethodiM Sulfoxide

Suppliers and Price of 5-Hydroxy-clethodiM Sulfoxide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 9 raw suppliers

Chemical Property of 5-Hydroxy-clethodiM Sulfoxide

Chemical Property:

Boiling Point:581.4±60.0 °C(Predicted)
PKA:3.55±0.42(Predicted)
PSA：111.91000
Density:1.29±0.1 g/cm3(Predicted)
LogP:3.39110

Purity/Quality:: > 95% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Uses 5-Hydroxy-clethodim Sulfoxide is an impurity of Clethodim (C573250), a post-emergent herbicide.

Technology Process of 5-Hydroxy-clethodiM Sulfoxide

There total 4 articles about 5-Hydroxy-clethodiM Sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: C₁₄H₂₂O₅S

: O-(3-chloro-2-propenyl)hydroxylamine

: 111031-08-4
C₁₇H₂₆ClNO₅S

Guidance literature:: In methanol; at -40 - 40 ℃; for 6h;

Reference yield:

: 36056-36-7
2-ethylthio methyl ester

: 111031-08-4
C₁₇H₂₆ClNO₅S

Guidance literature:: Multi-step reaction with 5 steps

1.1: lithium hydroxide monohydrate / methanol; tetrahydrofuran; water / 2 h / 20 °C

2.1: thionyl chloride / N,N-dimethyl-formamide; dichloromethane / 2 h / Reflux; Cooling with ice

3.1: n-butyllithium / tetrahydrofuran / 0.58 h / -60 - 20 °C

3.2: 2 h / -60 - 20 °C

4.1: dihydrogen peroxide / water; acetonitrile / 18 h / 0 - 20 °C

5.1: methanol / 6 h / -40 - 40 °C

With n-butyllithium; thionyl chloride; lithium hydroxide monohydrate; dihydrogen peroxide; In tetrahydrofuran; methanol; dichloromethane; water; N,N-dimethyl-formamide; acetonitrile;

Reference yield:

: 89534-40-7
3-ethylthio acid

: 111031-08-4
C₁₇H₂₆ClNO₅S

Guidance literature:: Multi-step reaction with 4 steps

1.1: thionyl chloride / N,N-dimethyl-formamide; dichloromethane / 2 h / Reflux; Cooling with ice

2.1: n-butyllithium / tetrahydrofuran / 0.58 h / -60 - 20 °C

2.2: 2 h / -60 - 20 °C

3.1: dihydrogen peroxide / water; acetonitrile / 18 h / 0 - 20 °C

4.1: methanol / 6 h / -40 - 40 °C

With n-butyllithium; thionyl chloride; dihydrogen peroxide; In tetrahydrofuran; methanol; dichloromethane; water; N,N-dimethyl-formamide; acetonitrile;