(1aS)-2β,7β-Methano-1aα,2,7,7aα-tetrahydronaphtho[2,3-b]oxirene

Base Information

• Chemical Name: (1aS)-2β,7β-Methano-1aα,2,7,7aα-tetrahydronaphtho[2,3-b]oxirene
• CAS No.: 13137-34-3
• Molecular Formula: C11H10O
• Molecular Weight: 158.1965
• Mol file: 13137-34-3.mol

Synonyms:(1aS)-2β,7β-Methano-1aα,2,7,7aα-tetrahydronaphtho[2,3-b]oxirene;1,2,3,4-Tetrahydro-2β,3β-epoxy-1β,4β-methanonaphthalene

Chemical Property of (1aS)-2β,7β-Methano-1aα,2,7,7aα-tetrahydronaphtho[2,3-b]oxirene

Chemical Property:

• Melting Point: 26 - 29 °C
• PSA: 12.53000
• LogP: 2.03850

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1aS)-2β,7β-Methano-1aα,2,7,7aα-tetrahydronaphtho[2,3-b]oxirene

There total 3 articles about (1aS)-2β,7β-Methano-1aα,2,7,7aα-tetrahydronaphtho[2,3-b]oxirene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

1,4-dihydro-1,4-methanonaphthalene (4453-90-1) → exo-benzonorbornadiene epoxide (13137-34-3)

Guidance literature:

With pyridine; dihydrogen peroxide; methyltrioxorhenium(VII); In dichloromethane; at 20 ℃; Inert atmosphere; Cooling with ice;

DOI:10.1016/j.tet.2010.04.029

Reference yield:

1,4-dihydro-1,4-methanonaphthalene (4453-90-1) → Benznorbornadien-oxyd (13137-34-3)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 - 20 ℃; for 12h;

DOI:10.3762/BJOC.16.148

Reference yield:

→ Benznorbornadien-oxyd (13137-34-3)

Guidance literature:

Benznorbornadien (I), Monoperphthalsaeure in Ae. bei 6grad;

DOI:10.1021/ja01490a051

upstream raw materials:

1,4-dihydro-1,4-methanonaphthalene

Downstream raw materials:

anti-benzonorbornen-9-ol