2,7-di(pyridin-4-yl)benzo[lMn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone

Base Information

• Chemical Name: 2,7-di(pyridin-4-yl)benzo[lMn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone
• CAS No.: 34151-49-0
• Molecular Formula: C24H12N4O4
• Molecular Weight: 420.384
• Mol file: 34151-49-0.mol

Synonyms:2,7-di(pyridin-4-yl)benzo[lMn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone;N,N'-Di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxdiimide

Chemical Property of 2,7-di(pyridin-4-yl)benzo[lMn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone

Chemical Property:

• Melting Point: 353°C(lit.)
• Boiling Point: 770.2±60.0 °C(Predicted)
• PKA: 6.03±0.10(Predicted)
• PSA: 103.92000
• Density: 1.588±0.06 g/cm3(Predicted)
• LogP: 1.83400

Purity/Quality:

97% ^*data from raw suppliers

N,N'-Di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxdiimide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,7-di(pyridin-4-yl)benzo[lMn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone

There total 2 articles about 2,7-di(pyridin-4-yl)benzo[lMn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

→ N,N-bis(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (34151-49-0)

Guidance literature:

In N,N-dimethyl-formamide; at 150 ℃; for 2h;

Reference yield: 84.0%

4-aminopyridine (504-24-5) + 1,4,5,8-naphthalenetetracarboxylic dianhydride (81-30-1) → N,N-bis(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (34151-49-0)

Guidance literature:

In N,N-dimethyl-formamide; for 6h; Heating;

DOI:10.1246/cl.2008.550

Reference yield: 90.0%

zinc(II) nitrate hexahydrate + terephthalic acid (100-21-0) + N,N-dimethyl-formamide (68-12-2,33513-42-7) + N,N-bis(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (34151-49-0) → {[Zn2(1,4-benzenedicarboxylic acid)2(N,N’-bis-(4-pyridyl)-1,4,5,8-naphthalene diimide)]*4DMF}n

Guidance literature:

at 95 ℃; for 72h;

DOI:10.1002/chem.201505217

upstream raw materials:

4-aminopyridine

1,4,5,8-naphthalenetetracarboxylic dianhydride

Downstream raw materials:

4-aminopyridine

1,2,3,6,7,8-hexahydropyrene-1,3,6,8-tetraone